硅杂环戊二烯并苯有机小分子化合物研究进展

doi:10.6023/cjoc201312008

摘要/Abstract

硅杂环戊二烯并苯有机小分子结构的特殊性，赋予其独特的光电特性，在有机光电功能材料等领域具有广阔的应用前景. 其中，并苯的刚性共平面结构可避免构象无序性、扩大π-共轭；硅杂环戊二烯能够形成σ^*-π^*共轭，可有效降低体系LUMO能级、提高电子亲合势. 硅杂环戊二烯并苯有机小分子主要包括苯并噻咯、硅桥联对二苯乙烯衍生物、二苯并噻咯和双硅桥联对-三联苯等. 综述了硅杂环戊二烯并苯小分子的合成方法、结构修饰、性能及应用的研究进展，并对今后的研究方向进行了展望.

关键词: 硅杂环戊二烯并苯, 硅桥联, π-共轭, 光电材料

Benzosilole-containing organic molecules have been potentially applied in opto-electronic material fields, due to their unique structural and optical characteristics. The rigid planar structures of acenes prevent conformational disorder, and extend the π-conjugation. Silacyclopentadiene can form σ^*-π^* conjugation, lowering the LUMO and enhancing the electron affinity efficiently. In this review, benzosiloles, silicon-bridged stilbene derivatives, silafluorenes and bis-silicon-bridged p-terphenyls are focused on. The recent research progress in the synthesis, modification, properties and applications of benzosilole-containing organic compounds is summarized, and the future research of this field is also prospected.

Key words: benzosilole, silicon-bridge, π-conjugated, opto-electronic materials

引用此文

曲红梅, 蒋丽丽, 陈涛, 唐建可. 硅杂环戊二烯并苯有机小分子化合物研究进展[J]. 有机化学, 2014, 34(6): 1061-1073.

Qu Hongmei, Jiang Lili, Chen Tao, Tang Jianke. Research Progress in Benzosilole-Containing Organic Compounds[J]. Chin. J. Org. Chem., 2014, 34(6): 1061-1073.

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