有机化学 ›› 2016, Vol. 36 ›› Issue (5): 1073-1079.DOI: 10.6023/cjoc201509040 上一篇    下一篇

研究论文

涉及碳-碳键断裂的克莱森-施密特缩合反应

杨永青, 朱孟楠, 陆征, 陈立婷, 苏静   

  1. 江苏大学药学院 镇江 212013
  • 收稿日期:2015-09-29 修回日期:2015-11-09 发布日期:2016-01-04
  • 通讯作者: 杨永青, 陆征 E-mail:yqy@ujs.edu.cn
  • 基金资助:

    国家自然科学基金(No.21572118)、江苏高校优势学科建设工程(PAPD)和江苏大学高级人才启动基金(Nos.10JDG042,14JDG018)资助项目.

Claisen-Schmidt Condensation Involved with C—C Bond Cleavage

Yang Yong-Qing, Zhu Meng-Nan, Lu Zheng, Chen Li-Ting, Su Jing   

  1. School of Pharmacy, Jiangsu University, Zhenjiang 212013
  • Received:2015-09-29 Revised:2015-11-09 Published:2016-01-04
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21572118), the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) and the Jiangsu University Startup Funding for Talented Researcher (Nos. 10JDG042, 14JDG018).

研究了BaOH2促进的β-二酮与芳香醛的克莱森-施密特反应,反应产物可能为单烯烃或双烯烃化合物.单烯烃的生成涉及碳-碳键的断裂,双烯烃产物是姜黄素的三元环类似物.

关键词: 克莱森-施密特缩合, 姜黄素, 碳-碳键断裂

Claisen-Schmidt condensation of β-diketone and aryl aldehyde is studied. The reaction product could be mono-or di-alkene. C—C bond cleavage is involved in the production of monoalkene. While the dialkene products are three-membered ring analogues of curcumin.

Key words: Claisen-Schmidt condensation, curcumin, C—C bond cleavage