有机化学 ›› 1988, Vol. 8 ›› Issue (2): 139-140. 上一篇    下一篇

研究论文

双核钴配合物(ROCH2C≡CCH2OR)Co2(CO)6的合成

孟庆金;孙守恒;步修仁;游效曾   

  1. 南京大学配位化学研究所
  • 发布日期:1988-04-25

Synthesis of dinuclear cobalt complexes (ROCH2C)2Co2(CO)6

MENG QINGJIN;SUN SHOUHENG;BU XIUREN;YOU XIAOZENG   

  • Published:1988-04-25

从羰基钴络合物Co2(CO)8与炔烃反应合成了一系列钴络合物(ROCH2C)2Co2(CO)6, R=Ac, PhCO, ClCH2CO, Ph-Ph, p-NO2Ph, β-C10H7,o-CH3CONHPh.

关键词: 乙酸酯, 二联苯, 羰基络合物, 苯甲酸 P, 乙酰胺 P, 钴络合物, 炔烃 P, 双核络合物

o-AcNHPh) were prepared in 40-80% yield by the reaction of CO2(CO)8 and (ROCH2C)2. The color of the obtained products was deep red to orange red. The IR, NMR, and UV spectra of the products were measured.

Key words: ACETIC ACID ESTER, BIPHENYL, CARBONYL COMPLEX, BENZENECARBOXYLIC ACID P, ACETAMIDE P, COBALT COMPLEX, ALKYNE P, DINUCLEAR COMPLEX

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