有机化学 ›› 1992, Vol. 12 ›› Issue (2): 164-168. 上一篇    下一篇

研究论文

1'-长链烷基取代吲哚啉螺苯并噻喃的合成及光谱性质

吴爱萍;明阳福;孟宪娟;樊美公   

  1. 中国科学院感光化学研究所
  • 发布日期:1992-04-25

Synthesis and spectral characteristics of some 1'-long chain alkyl substituted indolinospirobenzothiopyrans

WU AIPING;MING YANGFU;MENG XIANJUAN;FAN MEIGONG   

  • Published:1992-04-25

本文报道七个新的1'-长链烷基取代吲哚啉螺苯并噻喃衍生物的合成以及它们在溶液和高分子介质中的光致变色反应和吸收光谱性质。

关键词: 紫外分光光度法, 质子磁共振谱法, 质谱法, 缩合反应, 元素分析, 长链化合物, 十六碳化合物, 吸收光谱法, 巯基, 螺环化合物

Title compounds I (R1 = C16H33, C18H37; R2 = H, Me; R3 = H, MeO) were preparation by refluxing indolines II with benzaldehydes III in EtOH. Their m.p., elemental analyses, 1H NMR and mass spectra were studied to identify the structure of these new compounds The photochromic properties of all these compounds in solution and polymer media, as well as the absorption spectral properties of I and their ring opened from (merocyanines) were studied. The effects of the substituent and media on the spectral properties and the stability of merocyanines were also discussed.

Key words: CONDENSATION REACTION, ULTRAVIOLET SPECTROPHOTOMETRY, MASS SPECTROGRAPHY, C16 COMPOUNDS, LONG CHAIN COMPOUND, ELEMENTAL ANALYSIS, SPIRO COMPOUNDS, ABSORPTION SPECTROMETRY, MERCAPTO GROUP, PROTON MAGNETIC RESONANCE SPECTROMETRY

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