有机化学 ›› 1992, Vol. 12 ›› Issue (4): 378-381. 上一篇    下一篇

研究论文

查尔酮共轭体系紫外光谱的取代基效应

陆荣健;钟琦   

  1. 扬州师范学院化学系
  • 发布日期:1992-08-25

Substituent effect on the UV spectra of chalcone conjugated systems

LU RONGJIAN;ZHONG QI   

  • Published:1992-08-25

本文以取代查尔酮为标准系列,提出了一组新的取代基参数αP,并用αP研究了1,5-二取代芳基-1,3-戊二烯-5-酮系列化合物紫外光谱的取代基效应, 并初步探讨了 P与αP之间的关系。

关键词: 紫外分光光度法, 取代基效应, 共轭体系, 查耳酮, 戊二烯酮 P

Substituent constants (a) of chalcone conjugated compounds [I; R = H, m-NO2, p-Br, p-Ph; X = H, Me, MeO, Cl, NO2] were determine and showed a linear relationship with lmax. A linear relationship was also observed between the log of rate constants and Hammett reaction constant s with g > 0.98.

Key words: SUBSTITUENT EFFECT, ULTRAVIOLET SPECTROPHOTOMETRY, CHALCONE, PENTADIENONE P

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