有机化学 ›› 1993, Vol. 13 ›› Issue (2): 189-191. 上一篇    下一篇

研究论文

斯德酮化全物的反应

田宪儒   

  1. 成功大学化学系
  • 发布日期:1993-04-25

The reactions of sydonone compounds

TIAN XIANRU   

  • Published:1993-04-25

用3-苄基-4-苯基斯德酮和4-甲酰基-3-芳基斯德酮的硝化研究了在斯德酮环4-取代的去定域化效应和斯德酮环的电子效应的二重性。

关键词: 反应性, 电子效应, 硝基化, 离域化, 斯德酮

Benzylphenylsydnone I (X = Y = H) was nitrated to give I (X = 3-NO2, Y = H; X = 3-NO2, Y = 4-NO2; X = Y = 4-NO2; X = 2-NO2, Y = H). Formylphenylsydnones II (R = H, Me, MeO, R1 = H) were nitrated to give II (R1 = NO2) in 43-92% yield.

Key words: ELECTRONIC EFFECT, REACTIVITY, NITRATION, SYDNONE P

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