有机化学 ›› 1995, Vol. 15 ›› Issue (3): 259-262. 上一篇    下一篇

研究论文

取代环戊二烯基负离子的二茂铁甲酰化反应

焦纶基;刘桂宏;马玉道;董玉斌   

  1. 山东大学化学系
  • 发布日期:1995-06-25

Ferrocene formylation reaction of substituted cyclopentadienyl anion

JIAO LUNJI;LIU GUIHONG;MA YUDAO;DONG YUBIN   

  • Published:1995-06-25

本文以6,6-二烷基富烯与甲基锂, 芳基锂及烯丙基格式试剂反应所得的取代环戊二烯基负离子与二茂铁甲酰氯反应合成了10个新的富烯化合物, 并通过^1HNMR, IR及元素分析确定了它们的结构 .

关键词: 二茂铁, 环戊二烯基, 甲酰化, 负离子

The new fulvenes have been synthesized by the reactions of 6,6-dialkylfulvene with methyllithium, aryllithium and allyl Grignard reagent followed by treatment of ferrocene formyl chloride. On the basis of ^1H NMR, IR and elemental analysis, their structures were proposed.

Key words: FERROCENE, CYCLOPENTADIENYL GROUP, FORMYLATION, ANIONS

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