有机化学 ›› 1997, Vol. 17 ›› Issue (3): 252-255. 上一篇    下一篇

研究论文

南海软珊瑚Sarcophyton molle化学成分的研究

饶志刚;邓松之;李凤英;吴厚铭;石正双   

  1. 中国科学院广州化学研究所;中国科学院上海有机化学研究所
  • 发布日期:1997-06-25

Studies on the chemical constituents of the soft coral Sarcophyton molle from South China Sea

RAO ZHIGANG;DENG SONGZHI;LI FENGYING;WU HOUMING;SHI ZHENGSHUANG   

  • Published:1997-06-25

从中国南海软肉芝软珊瑚(Sarcophyton molle)中分离到七个化合物, 经紫外光谱(UV), 红外光谱(IR), 质谱(MS)和核磁共振光谱(1H NMR, 13C NMR)分析, 确定了其化学结构。它们是: 异新西松烯(1), (E, E, E)-7, 8-环氧-1-异丙基-4, 8, 12-三甲基-十四环-1,3, 11-三烯(2), 正十八烷酸(3), 鲨肝醇(4), 神经酰胺(5), 胸腺嘧啶(6), 胸腺嘧啶脱氧核苷(7)。其中化合物(2)为新化合物。本文是第一次报道软珊瑚Sarcophyton molle的化学成分。

关键词: 神经酰胺, 碳13核磁共振谱法, 异新松烯, 紫外分光光度法, 三烯, 软珊瑚, 核磁共振谱法, 化学成分, 胸腺嘧啶, 质谱法

Seven organic compounds have been isolated from the soft coral Sarcophyton molle collected from South China Sea. Their chemical structures have been identified by UV, IR, MS, 1H NMR and 13C NMR as isoneocembrene (1), (E, E, E)-7, 8-epoxy-1-isopropyl-4, 8, 12-trimethyl-cyclotetradeca-1, 3, 11-triene(2), stearic acid (3), batyl alcohol (4), sinumeramide (5), thymine(6) and thymidine (7). Compound (2) is a new compound. It is the first report about the chemical constituents of the soft coral Sarcophyton molle.

Key words: SINUMERAMIDE, CHEMICAL COMPOSITION, C13 NMR SPECTROMETRY, TRIENE, OCTADECOIC ACID (=OCTADECYLIC ACID), NMR SPECTROMETRY, SOFT CORAL, THYMINE, MASS SPECTROGRAPHY, ULTRAVIOLET SPECTROPHOTOMETRY

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