有机化学 ›› 2004, Vol. 24 ›› Issue (10): 1191-1199. 上一篇    下一篇

综述与进展

富勒烯稠合体与共轭聚合物作为有机太阳能电池材料的研究进展

霍延平a,b, 曾和平*,b, 江焕峰a,c   

  1. a中国科学院广州化学研究所 广州 510650;
    b华南师范大学化学系 广州 510631;
    c华南理工大学应用化学系 广州 510641
  • 收稿日期:2003-10-14 修回日期:2004-02-13 接受日期:2004-03-09 发布日期:2022-09-20
  • 基金资助:
    国家自然科学基金(No. 20231020)、广东省自然科学基金(No. 36585)重点资助项目.

Advances in Organic Solar Cell Based on Fullerene-dyad and Conjugated Polymer

HUO Yan-Pinga,b, ZENG He-Ping*,b, JIANG Huan-Fenga,c   

  1. aGuangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650;
    bDepartment of Chemistry, South China Normal University, Guangzhou 510631;
    cDepartment of Applied Chemistry, South China University of Technology,Guangzhou 510641
  • Received:2003-10-14 Revised:2004-02-13 Accepted:2004-03-09 Published:2022-09-20
  • Contact: * E-mail: zenghp@scnu.edu.cn

介绍了有关富勒烯与共轭聚合物超快光诱导电子的研究状况和三种不同光敏层材料制备的太阳能电池的组装和性能,包括:(1)以共轭聚合物/C60或C60衍生物的主体异介质为光敏层,(2)分子水平上的主体异介质:D-A双功能聚合物,(3)单纯以富勒烯稠合体为光敏层,以及国内外这三种太阳能电池研究的进展情况及存在的问题.

关键词: 富勒烯, 共轭聚合物, 太阳能电池, 电荷分离态, 光电转换效率, 主体异介质, 双功能聚合物

Ultrafast photoinduced electron transfer between fullerene and conjugated polymers was first introduced. The power conversion efficiency of solar cells based on three different types of active layers was discussed: (1) “Bulk-heterojunction” plastic solar cell based on conjugated polymer/fullerene; (2) Mocular heterojunction solar cell based on double-cable polymers; (3) Single component organic solar cell based on fullerene dyad. The main factors effecting the power conversion efficiency of solar cells were analyzed.

Key words: fullerene, conjugated polymer, solar cell, charge separated state, power conversion efficiency, bulk-heterojunction, double-cable polymer