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有机化学
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有机化学 ›› 2004, Vol. 24 ›› Issue (12): 1573-1576. 上一篇    下一篇

研究论文

脱氢姜黄烯及其类似物的合成

马军营a, 岳国仁a,b, 杜振亭a, 厍学功a, 武同兴a, 潘鑫复*,a   

  1. a兰州大学化学化工学院 功能有机分子化学国家重点实验室 兰州 730000
    b河西学院化学系 张掖 734000
  • 收稿日期:2003-10-21 修回日期:2004-06-03 接受日期:2004-06-03 发布日期:2022-09-20
  • 基金资助:
    国家自然科学基金(No. 20272053)、浙江省科技厅(No. 011101937)资助项目

Synthesis of Dehydrocurcumene and Its Analogue

MA Jun-Yinga, YUE Guo-Rena,b, DU Zhen-Tinga, SHE Xue-Gonga, WU Tong-Xinga, PAN Xin-Fu*,a   

  1. aState Key Laboratory of Applied Organic Chemistry, Department of Chemistry, Lanzhou University, Lanzhou 73000
    bDepartment of Chemistry, Hexi University, Zhangye 734000
  • Received:2003-10-21 Revised:2004-06-03 Accepted:2004-06-03 Published:2022-09-20
  • Contact: *E-mail: huyang@mail.hz.zj.cn

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利用苯乙酮及苯乙酮衍生物,经过傅-克乙酰化反应、偶联反应、Wittig烯化反应,合成了脱氢姜黄烯及其类似物.再经选择性催化氢化反应,可分别得到α-姜黄烯、黄根醇甲醚及姜黄氢醌甲醚.

关键词: 脱氢姜黄烯, 类似物, α-姜黄烯, 黄根醇甲醚, 姜黄氢醌甲醚, 合成

Using Friedel-Crafts acetylation reaction, coupling reaction and Wittig reaction, the dehydrocurcumene and its analogue have been synthesized. By selective catalytic hydrogenation followed, the corresponding α-curcumene, methyl curcuphenyl ether and methyl curcuhydroquinonyl ether were achieved, respectively.

Key words: dehydrocurcumene, analogue, α-curcumene, methyl curcuphenyl ether, methyl curcuhydroquinonyl ether, synthesis