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有机化学
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有机化学 ›› 2004, Vol. 24 ›› Issue (12): 1614-1618. 上一篇    下一篇

研究简报

醋酸锰作用下二烯丙基叔胺与[60]富勒烯的自由基环加成反应

邹远林, 张丹维, 刘颖, 罗政, 吴世晖, 高翔*   

  1. 复旦大学化学系 上海 200433
  • 收稿日期:2004-05-26 修回日期:2004-06-16 接受日期:2004-06-16 发布日期:2022-09-20
  • 基金资助:
    国家自然科学基金(No. 29872011)、教育部高等学校青年骨干教师基金和河北省教育厅科技基金(No. 990104)资助项目

Manganese(III) Acetate Based Radical Cycloaddition of Tertiary Diallylamines with [60]fullerene

ZOU Yuan-Lin, ZHANG Dan-Wei, LIU Ying, LUO Zheng, WU Shi-Hui, GAO Xiang*   

  1. Department of Chemistry, Fudan University, Shanghai 200433
  • Received:2004-05-26 Revised:2004-06-16 Accepted:2004-06-16 Published:2022-09-20
  • Contact: *E-mail: orgsyn@mail.hbu.edu.cn

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二烯丙基叔胺与[60]富勒烯在醋酸锰作用下发生自由基环加成反应,生成[60]富勒烯并吡咯烷衍生物.醋酸锰的用量和反应温度等因素对反应有一定影响.反应可能先由Mn(III)与烯丙胺经单电子氧化产生自由基,再与[60]富勒烯加成并进一步环化.研究中得到的各产物的结构均通过波谱学方法表征.

关键词: 醋酸锰, [60]富勒烯, 二烯丙基胺, 自由基环加成

The reaction of [60]fullerene with tertiary diallylamines in the presence of manganese(III) acetate dihydrate afforded [60]fulleropyrrolidine derivatives. The molar ratio of reagents and reaction temperature had somehow effects on the reaction. A possible mechanism of radical cycloaddition onto[60]fullerene initiated by one-electron oxidation of Mn(III) and diallylamines was proposed. The [60]fulleropyrrolidine derivatives prepared from the reactions were characterized by means of spectroscopic techniques.

Key words: manganese(III) acetate, [60]fullerene, diallylamine, radical cycloaddition