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有机化学
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有机化学 ›› 2006, Vol. 26 ›› Issue (08): 1130-1132. 上一篇    下一篇

研究简报

片呐醇电合成的研究

边延江*,1，杨卫民1，李记太2   

  1. (1廊坊师范学院化学系 廊坊 065000)
    (2河北大学化学系 保定 071002)
  • 收稿日期:2005-08-04 修回日期:2006-02-28 发布日期:2006-07-26
  • 通讯作者: 边延江

Studies on the Electrosynthesis of Pinacols

BIAN Yan-Jiang*,1,YANG Wei-Min1,LI Ji-Tai2   

  1. (1 Department of Chemistry, Langfang Normal College, Langfang 065000)
    (2 Department of Chemistry, Hebei University, Baoding 071002)
  • Received:2005-08-04 Revised:2006-02-28 Published:2006-07-26
  • Contact: BIAN Yan-Jiang

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被引次数

11 | 3

以铝合金为电极在酸性条件下电合成片呐醇, 探讨了电压、反应时间等对产率的影响. 最佳反应条件为: 电解电压为12 V, 反应时间60～80 min, 甲醇和盐酸(36%)用量各5 mL, 片呐醇的产率可达31%～81%.

关键词: 片呐醇, 铝合金电极, 电合成

Electrosynthesis of pinacols by aluminum alloy as electrode in acid condition was performed, with the influence of electric potential and time on pinacol yield explored. The optimal reaction conditions were electric potential 12 V, time 60～80 min, methanol 5 mL, hydrochloric acid (36%) 5 mL, with the yields of pinacols up to 31%～81%.

Key words: aluminum alloy electrode, pinacol, electrosynthesis