有机化学 ›› 2008, Vol. 28 ›› Issue (08): 1336-1347. 上一篇    下一篇

综述与进展

手性分子光开关研究进展

刘文杰 ; 曹德榕*   

  1. (华南理工大学化学科学学院 广州 510640)
  • 收稿日期:2007-07-16 修回日期:2007-11-29 发布日期:2008-08-18
  • 通讯作者: 曹德榕

Progress in Molecular Chiroptical Switches

LIU, Wen-Jie; CAO, De-Rong*   

  1. (College of Chemistry, South China University of Technology, Guangzhou 510640)
  • Received:2007-07-16 Revised:2007-11-29 Published:2008-08-18
  • Contact: CAO, De-Rong

介绍了近年来发展起来的不同类型的手性光开关分子, 如手性螺烯、偶氮苯、二芳基乙烯、螺吡喃、联二萘、俘精酸酐、胆红素-IIIα, 手性光致变色聚合物等; 讨论了分子手性光开关材料特殊的光致异构性质, 综述了该材料在信息存储等应用方面的研究状况, 并展望了手性光开关材料的研究前景.

关键词: 手性光开关, 光致异构, 信息存储

The different types of chiroptical switches are introduced, such as chiral helicene, azobenzene, diarylethene, spiropyran, binaphthyl compounds, fulgide and bilirubin-IIIα. Furthermore, their photoisomerization property and applications to the information storage are reviewed and their future foreground is also presented.

Key words: chiroptical switch, information storage, photoisomerization