有机化学 ›› 2008, Vol. 28 ›› Issue (12): 2023-2038.    下一篇

综述与进展

β-烷氧乙烯基三氟甲基酮类化合物在有机合成中的应用

陈 阳a; 水声霞a ; 方 向a ; 吴范宏*,a,b   

  1. (a华东理工大学化学与分子工程学院 结构可控先进功能材料及其制备重点实验室 上海 200237)
    (b中国科学院上海有机化学研究所 有机氟化学重点实验室 上海 200032)
  • 收稿日期:2008-01-22 修回日期:2008-04-07 发布日期:2008-12-28
  • 通讯作者: 吴范宏

Application of β-Alkoxyvinyl Trifluoromethyl Ketones to the Synthesis of Heterocycles

CHEN, Yanga ; SHUI, Sheng-Xiaa; FANG, Xianga; WU, Fang-Hong*,a,b   

  1. (a Laboratory for Advanced Material and Institute of Fine Chemicals, School of Chemistry and Molecular Engineering,
    East China University of Science and Technology, Shanghai 200237)
    (b Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry,
    Chinese Academy of Sciences, Shanghai 200032)
  • Received:2008-01-22 Revised:2008-04-07 Published:2008-12-28
  • Contact: WU, Fang-Hong

β-烷氧乙烯基三氟甲基酮类化合物作为一类典型的含氟砌块, 被广泛地应用于含氟有机化合物的合成中. 综述了近年来此类含氟砌块的研究进展, 特别是在合成各种含氟杂环化合物中的应用.

关键词: 含氟砌块, 杂环化合物, β-烷氧乙烯基三氟甲基酮

As a typical fluorine-containing building block, β-alkoxyvinyl trifluoromethyl ketones are broadly used to synthesize fluorine containing organic compounds. This paper reviewed the recent progress on the study of this synthon, including the application in the synthesis of fluorine-containing heterocycles.

Key words: heterocycle, fluorine-containing building block, β-alkoxyvinyl trifluoromethyl ketone