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有机化学
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有机化学 ›› 2009, Vol. 29 ›› Issue (04): 517-527. 上一篇    下一篇

综述与进展

螺共轭效应及其应用

魏荣宝*; 张大为 ; 刘 博; 刘 洋; 李文丽 ; 贾辰熙   

  1. (天津理工大学化学化工学院 天津 300191)
  • 收稿日期:1900-01-01 修回日期:1900-01-01 发布日期:2009-04-20
  • 通讯作者: 魏荣宝

Spiroconjugation Effect and Application

Wei, Rongbao* ; Zhang, Dawei ; Liu, Bo ; Liu, Yang; Li, Wenli ; Jia, Chenxi   

  1. (College of Chemistry & Chemical Engineering, Tianjin University of Technology, Tianjin 300191)
  • Received:1900-01-01 Revised:1900-01-01 Published:2009-04-20
  • Contact: Wei, Rongbao

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12 | 1

螺共轭术语是1967年由Simmons和Fukunaga首次提出的, 由于其特殊的立体电子效应而引起了科学家们的广泛关注. 综述了40年来有关螺共轭的理论发展以及在发光材料、光致变色材料、非线性光学材料、螺环染料、有机导体等方面的研究现状, 展望了螺共轭效应的应用前景, 并提出了一些新的设想.

关键词: 螺共轭, 螺环化合物, 应用, 电子光谱

The expression spiroconjugation was introduced in 1967 by Simmons and Fukunaga and has drawn great attention because of its unique steric electric effect. Spiroconjugation effect has an important value in organic light-emitting materials, light changed color materials, nonlinear optical materials, charge-transfer dyes and organic conductors. In this review, the progress in theory and application during recent 40 years has been described. The potential application of spiroconjugation together with some novel ideas is supplied.

Key words: spiroconjugation, spiro compound, electronic spectra, application