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有机化学
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有机化学 ›› 2003, Vol. 23 ›› Issue (11): 1282-1285. 上一篇    下一篇

研究论文

超声间接电氧化合成三种甲基苯甲醛

阚显文;陶海升;杜俊;周运友;方宾   

  1. 安徽师范大学化学与材料科学学院
  • 发布日期:2003-11-25

Synthesis of Three Methylbenzaldehydes from Dimethylbenzene by Indirect Electrooxidation under Ultrasound Irradiation

Kan Xianwen;Tao Haisheng;Du Jun;Zhou Yunyou;Fang Bin   

  1. College of Chemistry and Material Science, Anhui Normal University
  • Published:2003-11-25

PDF

521

被引次数

6

以Mn(II)/Mn(III)为氧化还原媒质，间接电氧化合成了邻、间、对位甲基苯甲 醛。在电解和合成的过程中，分别施加了超声进行反应。实验结果表明，电解的电 流效率和邻甲基苯甲醛、间甲基苯甲醛的合成产率在超声的参与下有10%左右的提 高。优化了超声电解的条件，并探讨了超声与未超声时将二甲苯的三个异构体氧化 为相应醛的难易程度。

关键词: 苯甲醛 P, 电解, 电氧化, 二甲苯, 异构体

o-, m-, p -Methylbenzaldehydes were syntliesized from dimethylbenzene with Mn(II)/ Mn(III) as the oxidant by indirect electrooxidation. Ultrasound was used in the process of electrolysis. The experimental results indicated that the current efficiency of electrolysis and the yields of o-, m- , p -methylbenzaldehydes were promoted about 10% under ultrasound irradiation. The conditions of ultrasound electrooxidation were optimized.

Key words: BENZALDEHYDE P;ELECTROLYSIS;ELECTROOXIDATION;DIMETHYLBENZENE, ISOMER

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