有机化学 ›› 2007, Vol. 27 ›› Issue (9): 1039-1059.    下一篇

综述与进展

金属卟啉催化剂应用于均相氧化反应的研究进展

周贤太a,纪红兵*,a,裴丽霞a,佘远斌b,徐建昌a,王乐夫a   

  1. (a华南理工大学化工与能源学院 广州 510640)
    (b北京工业大学绿色化学研究所 北京 100022)
  • 收稿日期:2005-11-01 修回日期:2007-01-02 发布日期:2007-08-30
  • 通讯作者: 纪红兵

Advance of Homogeneous Oxidation with Metalloporphyrins as Catalysts

ZHOU Xian-Taia,JI Hong-Bing*,a,PEI Li-Xiaa,SHE Yuan-Binb
XU Jian-Changa,WANG Le-Fua   

  1. (a School of Chemical and Energy Engineering, South China University of Technology, Guangzhou 510640)
    (b Institute of Green Chemistry, Beijing University of Technol-ogy, Beijing 100022)
  • Received:2005-11-01 Revised:2007-01-02 Published:2007-08-30
  • Contact: JI Hong-Bing

详细介绍了金属卟啉作为催化剂应用于各种均相氧化反应, 包括烷烃、烯烃、醇、醛、酚、硫化物、氮化物等化合物的氧化反应研究进展, 认为金属卟啉模拟酶催化剂在均相氧化反应中将有更大的应用前景.

关键词: 金属卟啉, 均相氧化, 仿生催化

The catalytic homogeneous oxidations of alkane, alkene, alcohol, aldehyde, phenol, sulfide and nitride by metalloporphyrins are reviewed. Metalloporphyrins were considered to be effective catalysts for homogeneous oxidation and would find many applications.

Key words: homogeneous oxidation, biomimetic catalysis, metalloporphyrin