有机化学 ›› 1994, Vol. 14 ›› Issue (5): 516-521. 上一篇    下一篇

研究论文

某些新型冠醚-卟啉化合物的合成

蓝仲薇;陈姜涛;余孝其   

  1. 四川大学化学系
  • 发布日期:1994-10-25

Synthesis of some new "crowned" porphyrin compounds

LAN ZHONGWEI;CHEN JIANGTAO;YU XIAOQI   

  • Published:1994-10-25

本文以内消旋不对称单羟基-卟啉化合物1a~d合成了七种新型的冠醚-卟啉化合物3a~g和它们的中间体2a~g.这些化合物中的某些金属络合物对链烯的环氧化作用起催化作用, 它们的结构经元素分析,IR, UV和^1H NMR波谱证实.

关键词: 催化活性, 中国石油化学工业总公司基金, 冠醚-卟啉

Seven new "crowned" porphyrin compounds 3a~g and their intermediates 2a~g were synthesized from meso- asymmetric monohydroxyl-porphyrin compounds 1a~d. Some metal complexes of these compounds are effective catalysts for the epoxidation of olefins. Their structures have been demonstrated by elemental analysis, IR, UV and ^1H NMR spectra.

Key words: CATALYTIC ACTIVITY

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