有机化学 ›› 2000, Vol. 20 ›› Issue (5): 750-753. 上一篇    下一篇

研究论文

2-(4-N-硝基,N-甲基氨基苯基)-(4-硝基苯基)-5-(2,4,6- 三硝基苯基)噻唑的 合成及其性能研究

赵雷;王世敏;张胜利;常俊丽;陈祖兴;孙俊梅;张干兵   

  1. 湖北大学化学与材料科学学院
  • 发布日期:2000-10-25

Study on synthesis and property of 2-(4-N-nitro-N-methylaminophenyl)- (4-nitrophenyl)-5- (2,4,6-trinitrophenyl)thiazole

Zhao Lei;Wang Shimin;Zhang Shengli;Chang Junli;Chen Zuxing;Sun Junmei;Zhang Ganbing   

  • Published:2000-10-25

为解决非线性光学活性有机分子透明性差及熔点低的问题,设计合成了2-(4-N-硝基,N-甲基氨基苯基)-(4-硝基苯基)-5-(2,4,6-三硝基苯基)噻唑化合物,并研究了其热性能及光学性质。根据实验结果得出由于杂环的引入,提高了化合物的裂解温度,并较好地改善了有机分子的透明性。

关键词: 热稳定性, 光学性质, 噻唑P, 光学活性有机分子, 杂环化合物, 透明度, 非线性光学

In order to resolve the problem of poor clarity and low melting temperature of organic nonlinear optical molecules, 2-(4-N-nitro-N- methylaminophenyl)-(4-nitrophenyl)-5- (2,4,6-trinitrophenyl)thiazole was designed and synthesized. The optical and thermal properties of this compound were analyzed. It was found that the decomposition temperature and the clarity were sugnificantly improved.

Key words: THERMAL STABILITY, OPTICAL PROPERTIES, THIAZOLE P, HETEROCYCLIC COMPOUNDS, TRANSPARENCY, NON LINEAR OPTICS

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