氟离子荧光探针设计、合成与应用的新进展

doi:10.6023/cjoc201606012

摘要/Abstract

近年来，生物体内外微量氟离子的识别与检测，受到了越来越多的关注.其中，由于荧光检测技术具有灵敏性高、选择性好、操作方便等优点，不断有各种新颖的氟离子荧光探针被设计与合成.根据荧光探针的结构特点和识别机制，将氟离子荧光探针分为去质子化型和反应型两大类，从绿色化学的观点出发，重点综述了近三年来国内外氟离子荧光探针在分子设计、合成与应用的新进展，并展望了氟离子荧光探针的发展方向.

关键词: 氟离子, 荧光探针, 分子设计, 合成, 绿色化学

The recognition and detection of trace fluoride ions in vivo and vitro have attracted great attention in recent years. More and more new fluorescent probes (FP) for fluoride ion detection have been designed and synthesized due to their advantages, such as high sensitivity, good selectivity and convenient operation. According to the different structural features and recognition mechanism, fluoride ion FP can be classified into two categories as deprotonation and reaction type. The new progress especially in recent three years on their molecular design, synthesis and application is reviewed on the viewpoint of green chemistry. The future trend of fluoride ion FP is also prospected.

Key words: fluoride ion, fluorescent probe, molecular design, synthesis, green chemistry

引用此文

张惠敏, 吴彦城, 尤嘉宜, 曹梁, 丁沙, 蒋凯, 汪朝阳. 氟离子荧光探针设计、合成与应用的新进展[J]. 有机化学, 2016, 36(11): 2559-2582.

Zhang Huimin, Wu Yancheng, You Jiayi, Cao Liang, Ding Sha, Jiang Kai, Wang Zhaoyang. New Progress in the Design, Synthesis and Application of Fluorescent Probes for Fluoride Ion Detection[J]. Chin. J. Org. Chem., 2016, 36(11): 2559-2582.

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