Janus异官能基笼型倍半硅氧烷的合成研究

doi:10.6023/cjoc201608032

有机化学 ›› 2017, Vol. 37 ›› Issue (3): 636-645.DOI: 10.6023/cjoc201608032 上一篇下一篇

研究论文

Janus异官能基笼型倍半硅氧烷的合成研究

彭军^a,b, 邢玉秀^a, 许凯^a

a 中国科学院广州化学研究所广东省电子有机聚合物材料重点实验室广州 510650;
b 广东工业大学轻工化工学院广州 510006

收稿日期:2016-08-31 修回日期:2016-11-22 发布日期:2016-12-02
通讯作者: 彭军,E-mail:pengjun3032@126.com;许凯,E-mail:xk@gic.ac.cn E-mail:pengjun3032@126.com;xk@gic.ac.cn
基金资助:
国家自然科学基金（No.21174162）、广东省自然科学基金（No.2016A030313162）及广州市科技计划（No.201505051006333）资助项目.

A Study on Synthesis of Janus Heterofunctional Cubic Silsesquioxanes

Peng Jun^a,b, Xing Yuxiu^a, Xu Kai^a

a Guangdong Provincial Key Laboratory of Organic Polymer Materials for Electronics, Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650;
b School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006

Received:2016-08-31 Revised:2016-11-22 Published:2016-12-02
Contact: 10.6023/cjoc201608032 E-mail:pengjun3032@126.com;xk@gic.ac.cn
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21174162), the Province Natural Science Fund of Guangdong Province (No. 2016A030313162) and the Guangzhou Science and Technology Plan Projects (No. 201505051006333).

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摘要/Abstract

设计合成确切结构的异官能基笼型倍半硅氧烷一直是国际性的研究热点问题.用"自下而上"的方法，以半笼型结构倍半硅氧烷为模板，成功地制备出具有Janus结构的四乙烯基四氨基苯基、四乙烯基四苯基异官能基笼型倍半硅氧烷.并且，产物在一些极性溶剂（如四氢呋喃、氯仿及二甲基亚砜）中有较好的溶解性，为其衍生化及应用提供了保证.对所制备的异官能基笼型倍半硅氧烷进行了全面的表征分析，证明其具有Janus异官结构特征及完整的笼型结构.紫外可见及荧光发射光谱证实了倍半硅氧烷笼型结构的电子携带及传输作用，反过来证明其具有完整的笼型结构，同时也为其在有机光电材料中应用提供可能.提供了一类通用合成方法，拓宽了倍半硅氧烷功能单体的种类，并拓展了其应用范围.

关键词: 异官能基笼型倍半硅氧烷, Janus纳米粒子, 功能单体

Design and synthesis of well-defined hetero-functional cubic silsesquioxane remain as international research focuses and challenges. In this work, we demonstrated in detail the synthesis of two Janus hetero-functional cubic silsesquioxane. We applied similar "bottom-up" method to construct the aimed Janus HFCSQ, which was carried out by using cyclic tetrasiloxanes as synthetic platforms and followed by further hydrolysis and cage-closure. The obtained products exhibited good solubility in THF, CHCl3 and DMSO, which embodied themselves potential use in further derivations and processing. The precise structure of these obtained Janus HFCSQ were fully characterized by FTIR, ¹H NMR, Maldi-tof MS, ²⁹Si NMR, WAXD and TGA. Red-shifts observed from Photoluminescence UV-vis analysis further confirmed extended conjugation of the silsesquioxane cages, which in turn proved the formation of completed cages.This work provided us a versatile novel method to prepare the resulting Janus HFCSQs, which can widely expand the species of silsesquioxane monomers and applications as well.

Key words: hetero-functional cubic silsesquioxane, Janus nanoparticle, functional monomer

引用此文

彭军, 邢玉秀, 许凯. Janus异官能基笼型倍半硅氧烷的合成研究[J]. 有机化学, 2017, 37(3): 636-645.

Peng Jun, Xing Yuxiu, Xu Kai. A Study on Synthesis of Janus Heterofunctional Cubic Silsesquioxanes[J]. Chin. J. Org. Chem., 2017, 37(3): 636-645.

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Janus异官能基笼型倍半硅氧烷的合成研究

A Study on Synthesis of Janus Heterofunctional Cubic Silsesquioxanes

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