钯催化氧杂降冰片烯与三氟硼酸钾盐的不对称开环反应

doi:10.6023/cjoc201912030

有机化学 ›› 2020, Vol. 40 ›› Issue (6): 1630-1637.DOI: 10.6023/cjoc201912030 上一篇下一篇

研究论文

钯催化氧杂降冰片烯与三氟硼酸钾盐的不对称开环反应

陶萍芳^a, 黄俊^a,b, 刘玉钊^a, 韦光明^a, 王艺菲^a, 韦贤生^a, 黄国保^a, 李秀英^a

a 玉林师范学院化学与食品科学学院广西农产资源化学与生物技术重点实验室广西玉林 537000;
b 南宁师范大学化学与材料学院南宁 530001

收稿日期:2019-12-22 修回日期:2020-03-11 发布日期:2020-03-31
通讯作者: 黄国保, 李秀英 E-mail:lzjx0915@163.com;lxya8401@163.com
基金资助:
国家自然科学基金（No.21961042）、广西自然科学基金（No.2018GXNSFAA294064）及广西农产资源化学与生物技术重点实验室开放基金（No.KF04）资助项目.

Palladium-Catalyzed Asymmetric Ring-Opening Reactions of Oxabenzonorbornadienes with Potassium Trifluoroborate Salts

Tao Pingfang^a, Huang Jun^a,b, Liu Yuzhao^a, Wei Guangming^a, Wang Yifei^a, Wei Xiansheng^a, Huang Guobao^a, Li Xiuying^a

a Guangxi Key Laboratory of Agricultural Resources Chemistry and Biotechnology, College of Chemistry and Food Science, Yulin Normal University, Yulin, Guangxi 537000;
b College of Chemistry and Materials, Nanning Normal University, Nanning 530001

Received:2019-12-22 Revised:2020-03-11 Published:2020-03-31
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21961042), the Natural Science Foundation of Guangxi Province (No. 2018GXNSFAA294064) and the Open Fund of Guangxi Key Laboratory of Agricultural Resources Chemistry and Biotechnology Research Grant (No. KF04).

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摘要/Abstract

开发了一种新型高效的钯催化的三氟硼酸钾盐与氧杂降冰片烯的不对称开环反应的方法.在温和的条件下，可得到相应的顺-2-芳基-1，2-二氢萘-1-醇产物，其产率良好，目标产物对映体选择性较高.

关键词: 氧杂降冰片烯, 三氟钾硼酸盐, 不对称开环反应

A new, versatile and highly efficient palladium-catalyzed asymmetric ring-opening reaction of oxabenzonor-bornadienes with a wide range of potassium trifluoroborate salts was developed. The corresponding cis-2-aryl-1,2-dihydronaphthalen-1-ol products were obtained in good yields with moderate to good enantioselectivities under mild conditions.

Key words: oxabenzonorbornadiene, trifluoroborate salt, asymmetric ring-opening reaction

引用此文

陶萍芳, 黄俊, 刘玉钊, 韦光明, 王艺菲, 韦贤生, 黄国保, 李秀英. 钯催化氧杂降冰片烯与三氟硼酸钾盐的不对称开环反应[J]. 有机化学, 2020, 40(6): 1630-1637.

Tao Pingfang, Huang Jun, Liu Yuzhao, Wei Guangming, Wang Yifei, Wei Xiansheng, Huang Guobao, Li Xiuying. Palladium-Catalyzed Asymmetric Ring-Opening Reactions of Oxabenzonorbornadienes with Potassium Trifluoroborate Salts[J]. Chinese Journal of Organic Chemistry, 2020, 40(6): 1630-1637.

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钯催化氧杂降冰片烯与三氟硼酸钾盐的不对称开环反应

Palladium-Catalyzed Asymmetric Ring-Opening Reactions of Oxabenzonorbornadienes with Potassium Trifluoroborate Salts

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