铑催化炔烃的迁移1,n-双硼化和烯基硼的迁移氢硼化

doi:10.6023/cjoc202300005

有机化学 ›› 2023, Vol. 43 ›› Issue (1): 368-370.DOI: 10.6023/cjoc202300005 上一篇下一篇

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铑催化炔烃的迁移1,n-双硼化和烯基硼的迁移氢硼化

陈常鹏, 朱少林^*()

南京大学化学化工学院南京 210093

发布日期:2023-01-04
通讯作者: 朱少林

Rhodium-Catalyzed Migratory 1,n-Diborylation of Alkynes and Migratory Hydroboration of Vinylboronates

Changpeng Chen, Shaolin Zhu()

School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093

Published:2023-01-04
Contact: Shaolin Zhu

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陈常鹏, 朱少林. 铑催化炔烃的迁移1,n-双硼化和烯基硼的迁移氢硼化[J]. 有机化学, 2023, 43(1): 368-370.

Changpeng Chen, Shaolin Zhu. Rhodium-Catalyzed Migratory 1,n-Diborylation of Alkynes and Migratory Hydroboration of Vinylboronates[J]. Chinese Journal of Organic Chemistry, 2023, 43(1): 368-370.

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图式1. 研究设想: 炔烃原位/远程双硼化以及多取代烯烃的迁移硼化

Scheme 1. Proof of concept: native-remote diborylation of alkynes and migratory hydroboration of alkenyl boronates

表1. 铑催化的炔烃迁移1,n-双硼化

Table 1. Rh-catalyzed migratory 1,n-diboronation of alkynes

表2. 铑催化的含硼烯烃的迁移氢硼化

Table 2. Rh-catalyzed migratory hydroboration of alkenyl boronates

图式2. 克级实验和合成应用

Scheme 2. Gram-scale experiment and synthetic application

参考文献 7

[1]	Sommer, H.; Julia-Hernandez, F.; Martin, R.; Marek, I. ACS Cent. Sci. 2018, 4, 153. doi: 10.1021/acscentsci.8b00005
[2]	Li, J.; Qu, S.; Zhao, W. Angew. Chem., Int. Ed. 2020, 59, 2360. doi: 10.1002/anie.201913281
[3]	Zhang, M.; Liu, Z.; Zhao, W. Angew. Chem., Int. Ed. 2023, 62, e202215455.
[4]	You, Y.; Ge, S. Angew. Chem., Int. Ed. 2021, 60, 20684. doi: 10.1002/anie.202107405
[5]	Wang, W.; Ding, C.; Yin, G. Nat. Catal. 2020, 3, 951. doi: 10.1038/s41929-020-00523-8
[6]	Gao, D.-W.; Gao, Y.; Shao, H.; Qiao, T.-Z.; Wang, X.; Sanchez, B. B.; Chen, J. S.; Liu, P.; Engle, K. M. Nat. Catal. 2019, 3, 23. doi: 10.1038/s41929-019-0384-6
[7]	Jin, S.; Liu, K.; Shuai Wang, S.; Song, Q. J. Am. Chem. Soc. 2021, 143, 13124. doi: 10.1021/jacs.1c04248

铑催化炔烃的迁移1,n-双硼化和烯基硼的迁移氢硼化

Rhodium-Catalyzed Migratory 1,n-Diborylation of Alkynes and Migratory Hydroboration of Vinylboronates

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