磷杂环戊二烯[1,5]-σ键迁移的新进展
收稿日期: 2012-08-27
修回日期: 2012-09-19
网络出版日期: 2012-09-24
基金资助
国家自然科学基金(No. 21072179)资助项目.
Recent Advances of [1,5]-Sigmatropic Shift of Phospholes
Received date: 2012-08-27
Revised date: 2012-09-19
Online published: 2012-09-24
Supported by
Project supported by the National Natural Science Foundation of China (No. 21072179).
磷杂环戊二烯在探索磷化学的研究中发挥了重要的作用, 并广泛应用于配位化学、催化和有机光电材料等领域. [1,5]-σ键迁移(以下简称[1,5]迁移)是磷杂环戊二烯的一类重要反应. 该迁移主要是由于磷杂环戊二烯弱的芳香性和环外磷上取代基的σ键与环内二烯体的反键轨道存在一定的σ-π*超共轭效应等特性所共同造成的. 该反应自发现以来就成为磷杂环戊二烯衍生化的重要和有效手段. 主要介绍了近几年来人们利用磷杂环戊二烯[1,5]迁移特性设计与合成新型有机磷化合物和含磷光电材料的研究进展.
关键词： 磷杂环戊二烯; [1,5]-σ键迁移; 有机磷
王丽丽 , 田荣强 , 段征 , Francois Mathey . 磷杂环戊二烯[1,5]-σ键迁移的新进展[J]. 有机化学, 2013 , 33(01) : 36 -45 . DOI: 10.6023/cjoc201208028
Phosphole plays an important role in the modern organophosphorus chemistry. Due to its structure specialities, the exocyclic P—R σ bond shows significant interaction with the π* orbital of the dienic system and this overlap favors the [1,5]-sigmatropic shift of the substitutent (R) of P from phosphorus to carbon. This provides an efficient method to prepare various functionalized phospholes. This review is concerning the recent application of [1,5]-sigmatropic shift of phospholes in the organophosphorus and material chemistry.
Key words： phosphole; [1,5]-sigmatropic shift; organophosphorus
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