无碱参与的铜催化芳基硼酸和硫酚的偶联反应研究
收稿日期: 2012-09-06
修回日期: 2012-10-17
网络出版日期: 2012-10-25
基金资助
浙江省自然科学基金(No. Y407081)资助项目.
Base-Free Cu(II)-Catalyzed Coupling Reaction of Arylboronic Acids and Thiols
Received date: 2012-09-06
Revised date: 2012-10-17
Online published: 2012-10-25
Supported by
Project supported by the Natural Science Foundation of Zhejiang Province (No. Y407081).
杨明华 , 裴吉 , 严国兵 , 翁秋月 . 无碱参与的铜催化芳基硼酸和硫酚的偶联反应研究[J]. 有机化学, 2013 , 33(02) : 343 -347 . DOI: 10.6023/cjoc201209008
Baes-free Cu(II)-catalyzed coupling reaction of arylboronic acid and thiols was described. After optimization of reaction conditions, such as solvents, reaction temperatures, copper salts and ligands, the results show that some biarylsulfides were synthesized in good yields using 1,10-phenanthroline-Cu(OAc)2·H2O as catalyst, DMSO/H2O (V: V＝1:1) as solvent, under air atmosphere at 60℃.
Key words： coupling reaction; thiol; arylboronic acid; 1,10-phenanthroline; cupric acetate
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