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2013 , Vol. 33 >Issue 08: 1834 - 1838

DOI: https://doi.org/10.6023/cjoc201301055

研究简报

双缩二氨基硫脲席夫碱锰配合物催化Henry反应的研究

  • 张鹏 ,
  • 何军 ,
  • 万宁宁 ,
  • 张维东 ,
  • 惠永海 ,
  • 解正峰
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  • a 石油天然气精细化工教育部&新疆维吾尔自治区重点实验室 新疆大学化学化工学院 乌鲁木齐 830046;
    b 中国石油独山子石化公司炼油厂 独山子 833600

收稿日期: 2013-01-22

  修回日期: 2013-03-23

  网络出版日期: 2013-04-07

基金资助

国家自然科学基金(Nos. 21262034, 20962018, 20862015, 20562011)资助项目.

收起

Bis-thiocarbohydrazones Schiff Base Mn(II) Complex as a Catalyst for Henry Reaction

  • Zhang Peng ,
  • He Jun ,
  • Wan Ningning ,
  • Zhang Weidong ,
  • Hui Yonghai ,
  • Xie Zhengfeng
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  • a Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education & Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Urumqi 830046;
    b Oil Refinery of Petrochina Dushanzi Petrochemical Company, Dushanzi 833600

Received date: 2013-01-22

  Revised date: 2013-03-23

  Online published: 2013-04-07

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21262034, 20962018, 20862015, 20562011).

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摘要

在室温下用双缩二氨基硫脲席夫碱锰(II)配合物催化了醛和硝基甲烷的Henry反应, 方便有效地合成了一系列的β-硝基醇. 具有反应条件温和、操作简单、产率高、催化剂用量少、且对环境友好等优点.

关键词： Henry反应; 醛; 硝基甲烷; 席夫碱

本文引用格式

张鹏 , 何军 , 万宁宁 , 张维东 , 惠永海 , 解正峰 . 双缩二氨基硫脲席夫碱锰配合物催化Henry反应的研究[J]. 有机化学, 2013 , 33(08) : 1834 -1838 . DOI: 10.6023/cjoc201301055

Abstract

Bis-thiocarbohydrazones Schiff base Mn(II) complex catalyzes the Henry reaction between aldehydes and nitromethane to afford β-nitroalcohol derivatives at room temperature. The remarkable advantages of this reaction were mild reaction conditions, simple workup procedure, high yield of products, less catalyst and environmental friendly.

Key words： Henry reaction; aldehydes; nitromethane; Schiff base

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