黄草乌中的新的二萜生物碱
收稿日期: 2014-01-09
修回日期: 2014-01-24
网络出版日期: 2014-02-14
基金资助
国家自然科学基金(No. 81273387)资助项目.
A New C19-Diterpenoid Alkaloid from Aconitum vilmorinianum
Received date: 2014-01-09
Revised date: 2014-01-24
Online published: 2014-02-14
Supported by
Project supported by the National Natural Science Foundation of China (No. 81273387).
从黄草乌(Aconitum vilmorinianum Kom.)中分离得到20个二萜生物碱,并应用HRESIMS,1D-和2D-NMR,单晶X射线衍射等方法确定了它们的结构. 其中一个为新的C19二萜生物碱,1-epi-16β-hydroxycardiopetaline,它是16β-hydroxycardiopetaline的差向异构体;19个为已知化合物.
唐天兴 , 陈东林 , 王锋鹏 . 黄草乌中的新的二萜生物碱[J]. 有机化学, 2014 , 34(5) : 909 -915 . DOI: 10.6023/cjoc201401013
A new C19-diterpenoid alkaloid, 1-epi-16β-hydroxycardiopetaline, together with 19 known diterpenoid alkaloids, was isolated from the roots of Aconitum vilmorinianum Kom. The structure of the new alkaloid was established on the basis of spectral data (HR-MS, X-ray crystallographic analysis, 1D- and 2D-NMR).
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