直接三氟甲硫基化反应研究进展
收稿日期: 2015-01-14
修回日期: 2015-02-09
网络出版日期: 2015-02-12
基金资助
国家自然科学基金(Nos. 21421002, 21332010, 21272036)和国家重点基础研究发展计划(No. 2012CB21600)资助项目.
Recent Advances of Direct Trifluoromethylthiolation
Received date: 2015-01-14
Revised date: 2015-02-09
Online published: 2015-02-12
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21421002, 21332010, 21272036) and the National Basic Research Program of China (No. 2012CB21600).
张柯 , 徐修华 , 卿凤翎 . 直接三氟甲硫基化反应研究进展[J]. 有机化学, 2015 , 35(3) : 556 -569 . DOI: 10.6023/cjoc201501017
Compounds containing trifluoromethylthio group (SCF3) play an important role in pharmaceuticals, agrochemicals and materials due to its strong electron-withdrawing effect and extremely high lipophilicity. Very recently, trifluoromethylthiolation has received a great attention. In this review, the new progress of direct trifluoromethylthiolation is described. Furthermore, the synthetic challenge for trifluoromethylthiolation is also discussed.
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