阳离子镱化合物催化合成2-氨基苯并噻嗪
收稿日期: 2017-09-26
修回日期: 2017-10-23
网络出版日期: 2017-11-15
基金资助
国家自然科学基金（No.21272168）资助项目.
Syntheses of 2-Amino-3,1-benzothiazines Catalyzed by Cationic Ytterbium Complex
Received date: 2017-09-26
Revised date: 2017-10-23
Online published: 2017-11-15
Supported by
Project supported by the National Natural Science Foundation of China (No. 21272168).
冯善娥 , 花露 , 姚志刚 , 徐凡 . 阳离子镱化合物催化合成2-氨基苯并噻嗪[J]. 有机化学, 2017 , 37(12) : 3257 -3261 . DOI: 10.6023/cjoc201709043
2-Amino-3,1-benzothiazine and its functionalized derivatives are known as useful compounds with a range of biological applications. A highly efficient reaction of o-aminocinnamate and isothiocyanates catalyzed by cationic ytterbium complex[Yb(CH3CN)9]3+[(AlCl4)3]3-·CH3CN under mild and solvent-free conditions was developed, which provides 2-amino-3,1-benzothiazines in high yields and chemoselectivity.
Key words： cationic complex; ytterbium; catalysis; 2-amino-3,1-benzothiazine
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