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2020 , Vol. 40 >Issue 1: 61 - 68

DOI: https://doi.org/10.6023/cjoc201905022

研究论文

钯催化二芳基膦氢对萘醌单酮的不对称1,4-加成反应

  • 孙贵救 ,
  • 肖繁花 ,
  • 段伟良
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  • a 上海应用技术大学化学与环境工程学院 上海 200237;
    b 扬州大学化学化工学院 江苏扬州 225002

收稿日期: 2019-05-11

  修回日期: 2019-08-29

  网络出版日期: 2019-09-12

基金资助

国家自然科学基金（Nos.21472218，21672183）资助项目.

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Palladium-Catalyzed Asymmetric 1,4-Addition of Diarylphosphines to Quinone Monoketals

  • Sun Guijiu ,
  • Xiao Fanhua ,
  • Duan Weiliang
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  • a School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418;
    b College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002

Received date: 2019-05-11

  Revised date: 2019-08-29

  Online published: 2019-09-12

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21472218, 21672183).

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摘要

研究了二芳基膦氢和萘醌单酮的不对称加成反应，在Pincer钯催化剂存在下，以中等到良好的产率和对映选择性合成了相应的手性膦化合物，进一步拓宽了Pincer钯催化剂的底物应用范围.

关键词： 钯催化; 二芳基磷氢; 不对称加成

本文引用格式

孙贵救 , 肖繁花 , 段伟良 . 钯催化二芳基膦氢对萘醌单酮的不对称1,4-加成反应[J]. 有机化学, 2020 , 40(1) : 61 -68 . DOI: 10.6023/cjoc201905022

Abstract

An asymmetric 1,4-addition reaction of diarylphosphines with quinone monoketals was studied. Pincer Pd complex was used as catalyst to generate a series of chiral phosphorus compounds with moderate to good enantioselectivities in high yields.

Key words： palladium catalysis; diarylphosphine; asymmetric addition

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