钯催化二芳基膦氢对萘醌单酮的不对称1,4-加成反应

doi:10.6023/cjoc201905022

有机化学 ›› 2020, Vol. 40 ›› Issue (1): 61-68.DOI: 10.6023/cjoc201905022 上一篇下一篇

研究论文

钯催化二芳基膦氢对萘醌单酮的不对称1,4-加成反应

孙贵救^a, 肖繁花^a, 段伟良^b

a 上海应用技术大学化学与环境工程学院上海 200237;
b 扬州大学化学化工学院江苏扬州 225002

收稿日期:2019-05-11 修回日期:2019-08-29 发布日期:2019-09-12
通讯作者: 肖繁花, 段伟良 E-mail:fhxiao@sit.edu.cn;duanwl@yzu.edu.cn
基金资助:
国家自然科学基金（Nos.21472218，21672183）资助项目.

Palladium-Catalyzed Asymmetric 1,4-Addition of Diarylphosphines to Quinone Monoketals

Sun Guijiu^a, Xiao Fanhua^a, Duan Weiliang^b

a School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418;
b College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002

Received:2019-05-11 Revised:2019-08-29 Published:2019-09-12
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21472218, 21672183).

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摘要/Abstract

研究了二芳基膦氢和萘醌单酮的不对称加成反应，在Pincer钯催化剂存在下，以中等到良好的产率和对映选择性合成了相应的手性膦化合物，进一步拓宽了Pincer钯催化剂的底物应用范围.

关键词: 钯催化, 二芳基磷氢, 不对称加成

An asymmetric 1,4-addition reaction of diarylphosphines with quinone monoketals was studied. Pincer Pd complex was used as catalyst to generate a series of chiral phosphorus compounds with moderate to good enantioselectivities in high yields.

Key words: palladium catalysis, diarylphosphine, asymmetric addition

引用此文

孙贵救, 肖繁花, 段伟良. 钯催化二芳基膦氢对萘醌单酮的不对称1,4-加成反应[J]. 有机化学, 2020, 40(1): 61-68.

Sun Guijiu, Xiao Fanhua, Duan Weiliang. Palladium-Catalyzed Asymmetric 1,4-Addition of Diarylphosphines to Quinone Monoketals[J]. Chinese Journal of Organic Chemistry, 2020, 40(1): 61-68.

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钯催化二芳基膦氢对萘醌单酮的不对称1,4-加成反应

Palladium-Catalyzed Asymmetric 1,4-Addition of Diarylphosphines to Quinone Monoketals

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