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2020 , Vol. 40 >Issue 10: 3044 - 3064

DOI: https://doi.org/10.6023/cjoc202005095

综述与进展

过渡金属催化不对称氧化反应方法研究进展

  • 姚彪 ,
  • 巫佳浩 ,
  • 汪钰 ,
  • 江焕峰
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  • 华南理工大学化学与化工学院 广东省功能分子工程重点实验室 广州 510641

收稿日期: 2020-05-31

  修回日期: 2020-07-06

  网络出版日期: 2020-08-11

基金资助

国家重点研发计划（No.2016YFA06002900）和广东省重点领域研发（No.2020B010188001）资助项目.

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Methods of Transition Metal-Catalyzed Asymmetric Oxidation

  • Yao Biao ,
  • Wu Jiahao ,
  • Wang Yu ,
  • Jiang Huanfeng
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  • Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641

Received date: 2020-05-31

  Revised date: 2020-07-06

  Online published: 2020-08-11

Supported by

Project supported by the National Key Research and Development Program of China (No. 2016YFA06002900) and the Key Research and Development Program of Guangdong Province (No. 2020B010188001).

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摘要

过渡金属催化的不对称氧化反应，作为不对称合成的重要研究内容之一，为手性天然产物和药物的合成提供了实用便捷途径，因此其方法研究备受人们关注.重点介绍了近年来过渡金属催化的烯烃不对称氧化官能团化反应、C—H键不对称氧化反应、不对称BV氧化反应和硫醚不对称氧化反应等研究进展，并展望其未来发展趋势.

关键词： 过渡金属催化; 不对称氧化; 对映选择性; 烯烃; 碳-氢活化

本文引用格式

姚彪 , 巫佳浩 , 汪钰 , 江焕峰 . 过渡金属催化不对称氧化反应方法研究进展[J]. 有机化学, 2020 , 40(10) : 3044 -3064 . DOI: 10.6023/cjoc202005095

Abstract

Transition metal-catalyzed asymmetric oxidation, as one of important research targets of chiral synthesis, provides a direct, practical route for the synthesis of various chiral bioactive products and drugs, and has received much attention. The recent progress of the methods of transition metal-catalyzed asymmetric oxidation, especially, asymmetric oxidative functionalization of olefins, C-H bond asymmetric oxidation reaction, asymmetric BV oxidation and sulfide asymmetric oxidation is elaborated. Outlook of those issuesis is also discussed.

Key words： transition metal catalysis; asymmetric oxidation; enantioselectivity; olefin; C-H activation

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