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2021 , Vol. 41 >Issue 10: 3880 - 3891

DOI: https://doi.org/10.6023/cjoc202105053

综述与进展

过渡金属催化的C—P键活化

  • 张凤萍 ,
  • 栾玉新 ,
  • 叶萌春
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  • 南开大学化学学院 元素有机化学国家重点实验室 天津 300071

收稿日期: 2021-05-31

  修回日期: 2021-07-12

  网络出版日期: 2021-07-26

基金资助

国家自然科学基金(21871145); 国家自然科学基金(91856104); 天津市自然科学基金(19JCZDJC37900)

收起

Transition Metal-Catalyzed C—P Bond Activation

  • Fengping Zhang ,
  • Yuxin Luan ,
  • Mengchun Ye
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  • State Key Laboratory and Institute of Elemento-organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071
* Corresponding authors. E-mail: ;

Received date: 2021-05-31

  Revised date: 2021-07-12

  Online published: 2021-07-26

Supported by

National Natural Science Foundation of China(21871145); National Natural Science Foundation of China(91856104); Natural Science Foundation of Tianjin City(19JCZDJC37900)

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摘要

过渡金属催化的C—P键活化转化为有机膦化合物的合成提供了一条经济、高效的途径, 近年来受到了越来越多的关注. 然而由于C—P键较高的键能和P原子强的配位性能, C—P键活化一直较为挑战. 采用不同的底物预活化方法和各类催化剂, 过渡金属催化的C—P键活化转化已经取得了显著的进展. 本综述将对该领域的发展进行总结, 按照反应机理和底物预活化策略的不同, 分类阐述这些反应的类型, 发展、特点和机理等.

关键词： 有机膦化合物; 过渡金属催化; C—P键活化

本文引用格式

张凤萍 , 栾玉新 , 叶萌春 . 过渡金属催化的C—P键活化[J]. 有机化学, 2021 , 41(10) : 3880 -3891 . DOI: 10.6023/cjoc202105053

Abstract

Transition metal-catalyzed C—P bond activation provides an ecomomical and high-efficient route for the synthesis of organic phosphine compounds, and has received increasing attention in recent years. Owing to high bond energy of C—P bond and strong coordinative ability of P atom, the activation of C—P bond has been a fomidable challenge. Relying on substrate-preactivation and various catalysts, great progress has been achieved. This review will give a summary of this field, and according to different mechanisms of C—P bond activation and strategies of substrate pre-activation, a detailed description on reaction type, development, characteristics and mechanism will be made.

Key words： organophosphines; transition metal; C—P bond activation

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