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2021 , Vol. 41 >Issue 12: 4725 - 4731

DOI: https://doi.org/10.6023/cjoc202111014

研究论文

可见光介导无金属的苯乙酸衍生物脱羧氘代

  • 何宇航 ,
  • 杨慧 ,
  • 高冬旭 ,
  • 马嘉慧 ,
  • 邵亚敏 ,
  • 安光辉 ,
  • 李光明
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  • 黑龙江大学化学化工与材料学院 功能无机材料化学重点实验室 哈尔滨 150080

收稿日期: 2021-11-06

  修回日期: 2021-12-11

  网络出版日期: 2021-12-15

基金资助

国家自然科学基金(21502046)

收起

Visible Light-Mediated Metal-Free Decarboxylative Deuteration of Carboxylic Acid

  • Yuhang He ,
  • Hui Yang ,
  • Dongxu Gao ,
  • Jiahui Ma ,
  • Yamin Shao ,
  • Guanghui An ,
  • Guangming Li
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  • Key Laboratory of Functional Inorganic Material Chemistry, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080
* Corresponding authors. E-mail: ;

Received date: 2021-11-06

  Revised date: 2021-12-11

  Online published: 2021-12-15

Supported by

National Natural Science Foundation of China(21502046)

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摘要

报道了无金属可见光诱导的苯乙酸衍生物脱羧. 在无添加剂条件下, 使用廉价的氘源成功地实现了酸的直接脱羧单氘化. 此外, 在空气存在时, 类似的催化体系能够通过脱羧氧化生成酮.

关键词： 光化学; 无金属; 脱羧; 氘代

本文引用格式

何宇航 , 杨慧 , 高冬旭 , 马嘉慧 , 邵亚敏 , 安光辉 , 李光明 . 可见光介导无金属的苯乙酸衍生物脱羧氘代[J]. 有机化学, 2021 , 41(12) : 4725 -4731 . DOI: 10.6023/cjoc202111014

Abstract

A metal-free visible light-induced decarboxylation of phenylacetic acid derivatives has been successfully developed. Without the additives, direct decarboxylative monodeuteration of acids was successfully achieved using cheap deuterium sources. Besides, in presence of air, similar catalytic systems provided ketone products.

Key words： photochemistry; metal-free; decarboxylation; deuteration

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