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2022 , Vol. 42 >Issue 5: 1431 - 1437

DOI: https://doi.org/10.6023/cjoc202112028

研究论文

烯烃自由基胺硒化: β-氨基硒醚的简易合成

  • 殷一樊 ,
  • 李晨 ,
  • 孙凯 ,
  • 刘颖杰 ,
  • 王薪
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  • a 新墨西哥州立大学化学与生物化学系 新墨西哥州 88011
    b 哈尔滨商业大学药学院 哈尔滨 150076
    c 烟台大学化学化工学院 山东烟台 264005

收稿日期: 2021-12-21

  修回日期: 2022-01-28

  网络出版日期: 2022-02-10

基金资助

国家自然科学基金(21801007)

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Radical Aminoselenation of Styrenes: Facile Access to β-Amido-selenides

  • Yifan Yin ,
  • Chen Li ,
  • Kai Sun ,
  • Yingjie Liu ,
  • Xin Wang
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  • a Department of Chemistry & Biochemistry, New Mexico State University, New Mexico, 88011 USA
    b School of Pharmacy, Harbin University of Commerce, Harbin 150076
    c College of Chemistry and Chemical Engineering, Yantai University, Yantai, Shandong 264005
*Corresponding authors. E-mail: ;

Received date: 2021-12-21

  Revised date: 2022-01-28

  Online published: 2022-02-10

Supported by

National Natural Science Foundation of China(21801007)

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摘要

发展了一种高效的烯烃、二芳基二硒醚和烷基胺的分子间胺硒化策略, 在铜盐和高价碘试剂条件下, 以较高产率获得一系列的β-氨基硒化物. 初步的实验结果表明, 反应涉及活性硒自由基中间体, 并提出了自由基反应机理.

关键词： 胺硒化; β-氨基硒化物; 活性硒化物; 自由基

本文引用格式

殷一樊 , 李晨 , 孙凯 , 刘颖杰 , 王薪 . 烯烃自由基胺硒化: β-氨基硒醚的简易合成[J]. 有机化学, 2022 , 42(5) : 1431 -1437 . DOI: 10.6023/cjoc202112028

Abstract

An efficient protocol for the intermolecular amidoselenation of alkenes with diphenyl diselenides and alkyl amines has been developed, affording a series of β-amido-selenides in high yields under copper salt and (diacetoxyiodo)benzene (PIDA) conditions. The preliminary experimental results supported the involvement of active selenide radical species, and a radical pathway was therefore proposed for the reaction.

Key words： amidoselenation; β-amido-selenide; active selenide; radical

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