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有机化学
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2023 , Vol. 43 >Issue 1: 17 - 35

DOI: https://doi.org/10.6023/cjoc202205018

综述与进展

电化学合成C-磺酰基化合物的研究进展

  • 魏琬絜 ,
  • 詹磊 ,
  • 高雷 ,
  • 黄国保 ,
  • 马献力
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  • a 桂林医学院 广西桂林 541199
    b 玉林师范学院 广西农产资源化学与生物技术重点实验室 广西玉林 537000

收稿日期: 2022-05-13

  修回日期: 2022-07-14

  网络出版日期: 2022-08-25

基金资助

国家自然科学基金(21961042); 广西自然科学基金(2021GXNSFBA075056); 广西高校中青年教师基础能力提升项目(2021KY0587); 广西高校中青年教师基础能力提升项目(2022KY0572); 广西高校中青年教师基础能力提升项目(2021KY0499); 玉林师范学院科研项目(G2021ZK16); 广西农产资源化学与生物技术重点实验室开放课题(2021KF01)

收起

Research Progress of Electrochemical Synthesis of C-Sulfonyl Compounds

  • Wanjie Wei ,
  • Lei Zhan ,
  • Lei Gao ,
  • Guobao Huang ,
  • Xianli Ma
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  • a Guilin Medical University, Guilin, Guangxi 541199
    b Guangxi Key Laboratory of Agricultural Resources Chemistry and Biotechnology, Yulin Normal University, Yulin, Guangxi 537000
* Corresponding authors. E-mail: ;

Received date: 2022-05-13

  Revised date: 2022-07-14

  Online published: 2022-08-25

Supported by

National Natural Science Foundation of China(21961042); Natural Science Foundation of Guangxi Province(2021GXNSFBA075056); Basic Ability Improvement Project of Young and Middle-aged Teachers in Guangxi Colleges(2021KY0587); Basic Ability Improvement Project of Young and Middle-aged Teachers in Guangxi Colleges(2022KY0572); Basic Ability Improvement Project of Young and Middle-aged Teachers in Guangxi Colleges(2021KY0499); Research Project of Yulin Normal University(G2021ZK16); Open Project of Guangxi Key Laboratory of Agricultural Resources Chemistry and Biotechnology(2021KF01)

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摘要

磺酰基化合物是一类重要的有机硫化合物, 在医药、农药和功能材料等领域中均具有广泛的应用, 因此, 有效的磺酰基化合物的合成策略已成为化学工作者们广泛研究的热点. 有机电化学合成是一种绿色、温和、高效的合成策略, 其在磺酰基化合物的合成中显示出了巨大的潜力. 本综述介绍了近年来利用电化学手段合成C-磺酰基化合物的反应. 按照电化学合成C(sp)-磺酰基化合物、C(sp2)-磺酰基化合物以及C(sp3)-磺酰基化合物的反应进行了分类归纳讨论, 并对相应的反应机理进行了阐述, 为今后此类反应在有机合成中的应用提供参考.

关键词： 有机电化学; 磺酰基化合物; 磺酰化

本文引用格式

魏琬絜 , 詹磊 , 高雷 , 黄国保 , 马献力 . 电化学合成C-磺酰基化合物的研究进展[J]. 有机化学, 2023 , 43(1) : 17 -35 . DOI: 10.6023/cjoc202205018

Abstract

Sulfonyl compounds are important organic sulfur compounds, which are widely used in the fields of medicine, pesticides, functional materials and so on. Therefore, efficient strategies for the synthesis of sulfonyl compounds have become the focus of extensive research. Organic electrochemical synthesis is a green, mild and efficient synthesis strategy, which shows great potential in the synthesis of sulfonyl compounds. The reactions of electrochemical synthesis of C-sulfonyl compounds in recent years are introduced. The reactions of electrochemical synthesis of C(sp)-sulfonyl compounds, C(sp2)-sulfonyl compounds and C(sp3)-sulfonyl compounds are classified, summarized and discussed, and the corresponding reaction mechanism is described, so as to provide reference for the application of such reactions in organic synthesis in the future.

Key words： organic electrochemistry; sulfonyl compounds; sulfonylation

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