对烷氧基酚的合成及其去芳构化后的合成应用
收稿日期: 2022-09-11
修回日期: 2022-11-09
网络出版日期: 2022-12-14
基金资助
河南省科技厅高等学校学科创新引智基地(HNGD2021047); 河南省教育厅高等学校重点科研(21A350008)
Synthesis of p-Alkoxy Phenol and Its Application after Dearomatization
Received date: 2022-09-11
Revised date: 2022-11-09
Online published: 2022-12-14
Supported by
Project from University Discipline Innovation and Talent Introduction Base of Science and Technology Department of Henan Province(HNGD2021047); Key Scientific Research Project of Henan Provincial Department of Education(21A350008)
户晓兢 , 郭斐翔 , 朱润青 , 周柄棋 , 张涛 , 房立真 . 对烷氧基酚的合成及其去芳构化后的合成应用[J]. 有机化学, 2023 , 43(6) : 2239 -2244 . DOI: 10.6023/cjoc202209012
p-Alkoxy phenol (p-AOPs) compounds were obtained by one-step selective hydroxylation of alkoxyl-aryl ethers with the transition metal ruthenium(II) as catalyst and [bis(trifluoroacetoxy)iodo]benzene (PIFA) as oxidant. These p-AOPs could be easily converted to quinone monoacetals (QMAs) after dearomatization. Condensation of the QMAs with β-naphthols provided polycyclic benzofurans which have a wide application prospect. The protocol established in this paper offered a facile and reliable way for the synthesis of these important compounds.
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