O2促进下五元环烯胺的C—H亚胺化
收稿日期: 2022-12-19
修回日期: 2023-01-22
网络出版日期: 2023-03-17
基金资助
安徽省教育厅质量工程(2020kfkc362); 滁州城市职业学院平台(2023zkzd05)
O2-Enabled C—H Imination of Five-Membered Cyclic Enamines
Received date: 2022-12-19
Revised date: 2023-01-22
Online published: 2023-03-17
Supported by
Quality Engineering Project of Anhui Provincial Education Department(2020kfkc362); Platform Project of Chuzhou City Vocation College(2023zkzd05)
范威 . O2促进下五元环烯胺的C—H亚胺化[J]. 有机化学, 2023 , 43(7) : 2492 -2498 . DOI: 10.6023/cjoc202212025
An O2-enabled C—H imination of five-membered cyclic enamines is reported. Metal-free catalytic three- component reactions of tetronic acid- or 1,3-cyclopentanedione-derived enaminones with arylglyoxals and arylamines worked well under microwave irradiation, furnishing a series of α-enamino-α-aroyl imines with good yields and complete stereoselectivity. In this reaction process, air serves as the green oxidant with water as the sole byproduct.
Key words： three component; regioselective imination
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