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2023 , Vol. 43 >Issue 10: 3635 - 3643

DOI: https://doi.org/10.6023/cjoc202304035

研究论文

镍催化苯并硅杂环丁烷与酰基硅烷的[4＋2]环化反应

  • 张维露 ,
  • 陈绍维 ,
  • 沈晓
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  • a 武汉大学高等研究院 武汉 430072
    b 有机硅化合物及材料教育部工程研究中心 武汉 430072

收稿日期: 2023-04-28

  修回日期: 2023-06-24

  网络出版日期: 2023-07-13

基金资助

国家重点研究发展计划(2022YFA1506100); 中央高校基本科研基金(2042023kf1010); 中央高校基本科研基金(2042023kf0202); 国家自然科学基金(21901191)

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Nickel-Catalyzed [4＋2] Cyclization of Benzosilacyclobutenes and Acylsilanes

  • Weilu Zhang ,
  • Shaowei Chen ,
  • Xiao Shen
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  • a Institute for Advanced Studies, Wuhan University, Wuhan 430072
    b Engineering Research Center of Organosilicon Compounds & Materials, Ministry of Education, Wuhan 430072
*E-mail:

Received date: 2023-04-28

  Revised date: 2023-06-24

  Online published: 2023-07-13

Supported by

National Key R&D Program of China(2022YFA1506100); Fundamental Research Funds for the Central Universities(2042023kf1010); Fundamental Research Funds for the Central Universities(2042023kf0202); National Natural Science Foundation of China(21901191)

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摘要

报道了镍催化苯并硅杂环丁烷与酰基硅烷的[4＋2]环化反应, 合成了环状双硅化合物. 该反应条件温和, 表现出较好的底物普适性, 产物还可以通过一步转化合成单醇或二醇化合物.

关键词： 镍催化; 苯并硅杂环丁烷; 酰基硅烷; 环加成反应; 碳硅键活化

本文引用格式

张维露 , 陈绍维 , 沈晓 . 镍催化苯并硅杂环丁烷与酰基硅烷的[4＋2]环化反应[J]. 有机化学, 2023 , 43(10) : 3635 -3643 . DOI: 10.6023/cjoc202304035

Abstract

A nickel-catalyzed [4＋2] cyclization reaction between benzosilacyclobutenes and acylsilanes for the synthesis of cyclic bissilanes is reported. The mild reaction showes good substrate scope and the products can be transformed to monoaclohols or diols via one-step down-stream transformations.

Key words： nickel catalysis; benzosilacyclobutene; acylsilane; cycloaddition; C—Si bond activation

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