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2024 , Vol. 44 >Issue 2: 622 - 630

DOI: https://doi.org/10.6023/cjoc202306014

研究论文

氮杂环卡宾催化的五氟苯基硫醚的合成

  • 夏登鹏 ,
  • 罗锦昀 ,
  • 何林 ,
  • 蔡志华 ,
  • 杜广芬
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  • 石河子大学化学化工学院 新疆石河子 832000

收稿日期: 2023-06-18

  修回日期: 2023-09-12

  网络出版日期: 2023-10-26

基金资助

国家自然科学基金(21662029); 石河子大学国际合作(GJHZ202204)

收起

N-Heterocyclic Carbene-Catalyzed Synthesis of Pentafluorophenyl Sulfides

  • Dengpeng Xia ,
  • Jinyun Luo ,
  • Lin He ,
  • Zhihua Cai ,
  • Guangfen Du
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  • School of Chemistry and Chemical Engineering, Shihezi University, Shihezi, Xinjiang 832000
* Corresponding authors. ;

Received date: 2023-06-18

  Revised date: 2023-09-12

  Online published: 2023-10-26

Supported by

National Natural Science Foundation of China(21662029); International Cooperation Project of Shihezi University(GJHZ201801)

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摘要

利用氮杂环卡宾催化剂的强Lewis碱性, 发展了一种构建C(sp2)—S键的有效方法. 稳定的氮杂环卡宾1,3-双(2,6-二异丙基苯基)咪唑-2-亚基可以对五氟苯基三甲基硅烷的C—Si键进行有效活化, 进而引发与硫代磺酸酯的亲核取代反应, 以34%~98%的产率生成五氟苯基硫醚产物.

关键词： 氮杂环卡宾; C—S键; 五氟苯基硫醚

本文引用格式

夏登鹏 , 罗锦昀 , 何林 , 蔡志华 , 杜广芬 . 氮杂环卡宾催化的五氟苯基硫醚的合成[J]. 有机化学, 2024 , 44(2) : 622 -630 . DOI: 10.6023/cjoc202306014

Abstract

An efficient method for the construction of C(sp2)—S bond has been developed. The stable N-heterocyclic carbene 1,3-bis(2,6-dissopropylphenyl)-imidazole-2-ylidene can activate the C—Si bond of pentafluorophenyl trimethylsilicon effectively to initiate the nucleophilic substitution reaction with thiosulfonic ester, producing pentafluorophenyl sulfide products in 34%~98% yields.

Key words： N-heterocyclic carbene; C—S bond; pentafluorophenyl sulfide

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