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2024 , Vol. 44 >Issue 12: 3609 - 3620

DOI: https://doi.org/10.6023/cjoc202405021

综述与进展

有机膦催化合成中环化合物的研究进展

  • 潘旭玲 ,
  • 黄有
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  • 南开大学化学学院 元素有机化学国家重点实验室 天津 300071

收稿日期: 2024-05-15

  修回日期: 2024-06-15

  网络出版日期: 2024-07-18

基金资助

国家自然科学基金(22171147); 国家自然科学基金(21871148)

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Progress in Synthesis of Medium-Sized Ring Compounds Catalyzed by Organophosphine

  • Xuling Pan ,
  • You Huang
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  • State Key Laboratory and Institute of Elemento-organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071
*Corresponding authors. E-mail:

Received date: 2024-05-15

  Revised date: 2024-06-15

  Online published: 2024-07-18

Supported by

National Natural Science Foundation of China(22171147); National Natural Science Foundation of China(21871148)

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摘要

中环(7~11元环)是一类重要的有机分子骨架, 广泛存在于药物、农药以及许多具有生物活性的天然产物中, 在有机合成化学中占有重要地位. 有机小分子催化反应是合成中环化合物的重要方法之一, 其中, 有机膦催化具有成本低廉、环境友好以及催化剂易于回收利用等优点, 为中环化合物的合成提供了一条经济而高效的途径. 因此, 近几十年来, 该研究领域受到了持续而广泛的关注. 本综述将对有机膦催化合成中环化合物的研究进展进行总结, 详细阐述不同反应底物类型、反应机理等.

关键词： 有机催化; 膦催化剂; 环化反应; 中环化合物

本文引用格式

潘旭玲 , 黄有 . 有机膦催化合成中环化合物的研究进展[J]. 有机化学, 2024 , 44(12) : 3609 -3620 . DOI: 10.6023/cjoc202405021

Abstract

Medium-sized rings (7~11 membered ring) are a class of important skeleton in organic molecules, which are commonly found in drugs, pesticides and many biologically active natural products, and play essential roles in organic synthetic chemistry. Organo-catalysis is an important methodology for the synthesis of medium-sized ring compounds, among which, organophosphine catalysis has the advantages of low cost, environmental friendliness, and easy recycling, which provides an economical and efficient route for the synthesis of medium-sized ring compounds. Therefore, this field of research has received continuous and extensive attention in recent decades. In this review, the research progress on the organophosphine-catalyzed synthesis of medium-sized ring compounds is summarized, detailing the different types of reaction substrates, reaction mechanisms, etc.

Key words： organocatalysis; phosphine catalysts; annulation reaction; medium-sized ring compounds

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