可见光引发炔烃双官能化反应构筑菲类化合物
收稿日期: 2024-07-03
修回日期: 2024-08-13
网络出版日期: 2024-09-02
基金资助
福厦泉国家自主创新协同创新项目(3502ZCQXT2021006); 高等学校学科创新引智计划(111计划); 高等学校学科创新引智计划(BC2018061); 华侨大学开放基金(AACCT0007)
Easy Access to Phenanthrenes Through Photoinduced Difunctionalization of Alkynes
Received date: 2024-07-03
Revised date: 2024-08-13
Online published: 2024-09-02
Supported by
Fuxiaquan National Independent Innovation Collaborative Innovation Project(3502ZCQXT2021006); Program of Introducing Talents of Discipline to Universities (111 Project); Program of Introducing Talents of Discipline to Universities(BC2018061); Open Research Fund of Huaqiao University(AACCT0007)
李梦倩 , 吕喆 , 王少君 , 韩宇轩 , 崔秀灵 . 可见光引发炔烃双官能化反应构筑菲类化合物[J]. 有机化学, 2025 , 45(2) : 686 -693 . DOI: 10.6023/cjoc202407009
Ketoesters were successfully utilized as the bifunctionalization reagents to react with diaryl alkynes under visible light and photocatalyst or additives free conditions. A series of phenanthrenes containing acyl and ester groups were obtained in high yields. This protocol features with excellent regioselectivity, high efficiency, and atomic economy.
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