SBA-15负载的N-杂环卡宾-吡啶钼配合物在二氧化碳转化制备环状碳酸酯中的应用
收稿日期: 2024-05-27
修回日期: 2024-07-31
网络出版日期: 2024-09-02
基金资助
国家自然科学基金(22168034); 新疆自治区天池英才计划; 石河子大学高层次人才科研启动资金(2022ZK001); 第七师胡杨河市科技计划(QS2024013)
N-Heterocyclic Carbene-Pyridine Molybdenum Complex Supported over SBA-15 for Converting of Carbon Dioxide into Cyclic Carbonates
Received date: 2024-05-27
Revised date: 2024-07-31
Online published: 2024-09-02
Supported by
National Natural Science Foundation of China(22168034); Tianchi Talent Project of Xinjiang Uygur; Start-Up Foundation for High-Level Professionals of Shihezi University(2022ZK001); Science and Technology Project of 7th Division Huyanghe City(QS2024013)
李建文 , 王涛 , 陶晟 , 陈飞 , 李敏 , 刘宁 . SBA-15负载的N-杂环卡宾-吡啶钼配合物在二氧化碳转化制备环状碳酸酯中的应用[J]. 有机化学, 2024 , 44(10) : 3213 -3222 . DOI: 10.6023/cjoc202405037
Synthesis of cyclic carbonates from carbon dioxide (CO2) and epoxides is an effective pathway for the CO2 utilization. Although various metal catalysts have been reported, it is highly desirable to develop a method for the reuse or recycling of catalysts. Herein, an N-heterocyclic carbene-pyridine molybdenum complex supported over SBA-15 (Mo@SBA- 15) was used as an efficient and recyclable catalyst for converting CO2 and epoxides into cyclic carbonates. Mo@SBA-15 in combination with tetra-butylammonium bromide (TBAB) shows high catalytic activity in the synthesis of cyclic carbonates under 100 ℃ and 1 MPa CO2 pressure. In addition, Mo@SBA-15 was reused seven times without any significant activity loss.
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