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2024 , Vol. 44 >Issue 10: 3091 - 3105

DOI: https://doi.org/10.6023/cjoc202406044

综述与进展

可再生能源驱动的CO2基环状碳酸酯合成研究进展

  • 许立锋 ,
  • 武安国 ,
  • 于芳羽 ,
  • 李红茹 ,
  • 何良年
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  • a 南开大学化学学院 元素有机化学国家重点实验室 天津 300071
    b 南开大学药学院 天津 300353

收稿日期: 2024-06-28

  修回日期: 2024-07-24

  网络出版日期: 2024-09-02

基金资助

国家重点研发计划(2022YFB4101800); 国家自然科学基金(22361132527)

收起

Progress on Renewable Energy-Driven Synthesis of Cyclic Carbonates from CO2

  • Lifeng Xu ,
  • Anguo Wu ,
  • Fangyu Yu ,
  • Hongru Li ,
  • Liangnian He
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  • a State Key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin 300071
    b College of Pharmacy, Nankai University, Tianjin 300353
*E-mail: ;

Received date: 2024-06-28

  Revised date: 2024-07-24

  Online published: 2024-09-02

Supported by

National Key Research and Development Program of China(2022YFB4101800); National Natural Science Foundation of China(22361132527)

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摘要

环状碳酸酯是重要的化工产品, 在电池电解液、化妆品、油漆等领域具有广泛应用, 同时还是有机合成的绿色溶剂和反应原料. 环状碳酸酯是工业规模CO2转化的重要产品, 主要通过环氧化物与CO2的环加成反应进行制备. 在传统的热催化反应中, 由于环氧化物活化开环具有较高的能垒, 因而一般需要较高的反应温度. 近年来, 新材料的发展推动了环加成反应催化剂的创新, 新的催化模式不断出现, 尤其是光驱动和电驱动的环加成反应实现了温和条件下环状碳酸酯的制备. 此外, 电驱动的烯烃或邻二醇与CO2合成环状碳酸酯也取得了初步的研究成果. 总结了光/电驱动的CO2合成环状碳酸酯的反应, 旨在通过对材料设计和催化机理的介绍, 为新型反应路径和催化材料的设计提供新思路.

关键词： 二氧化碳; 催化活化; 可再生能源; 环状碳酸酯; 光热协同

本文引用格式

许立锋 , 武安国 , 于芳羽 , 李红茹 , 何良年 . 可再生能源驱动的CO2基环状碳酸酯合成研究进展[J]. 有机化学, 2024 , 44(10) : 3091 -3105 . DOI: 10.6023/cjoc202406044

Abstract

The cyclic carbonate is a crucial chemical product extensively employed in battery electrolytes, cosmetics, paints, and various other industries. Additionally, it serves as an eco-friendly solvent and reaction precursor for organic synthesis. As the commercial products via CO2 conversion, cyclic carbonates were mainly prepared through the cycloaddition reaction of epoxides with CO2. By far, the production of cyclic carbonates still relies on the thermal catalytic cycloaddition reactions, in which high temperature is always required due to the high energy barrier for the ring-opening of epoxides and CO2 activation. In recent years, novel catalytic pathways have been proposed accompanied with the emergence of new catalytic materials. Especially the light/electricity-driven cycloaddition reactions render the synthesis of cyclic carbonates under room tem- perature. In addition, achievements have also been made on electron-induced cyclic carbonate synthesis from olefins or vicinal diols and CO2. The present review provides a comprehensive overview of the photocatalytic/electrocatalytic synthesis of cyclic carbonates from CO2, aiming to offer novel insights into the design of innovative reaction pathways and catalytic materials by incorporating material engineering and catalytic mechanisms.

Key words： carbon dioxide; catalytic activation; renewable energy; cyclic carbonate; photothermal synergy

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