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2024 , Vol. 44 >Issue 10: 3159 - 3168

DOI: https://doi.org/10.6023/cjoc202406038

研究论文

可见光促进烯烃与丙二酸酯、CO2的碳-羧化反应研究

  • 张澳龙 ,
  • 杨晗 ,
  • 程佩栋 ,
  • 姚阳 ,
  • 孙松
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  • 常州大学石油化工学院 江苏省先进催化与绿色制造协同创新中心 江苏常州 213164

收稿日期: 2024-06-27

  修回日期: 2024-09-05

  网络出版日期: 2024-09-19

基金资助

国家自然科学基金(21602019); 环保功能吸附材料制备技术国地联合工程实验室开放基金(SDGC2125)

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Visible-Light Photoredox-Catalyzed Carbon/Carboxylation of Alkenes with Malonates and CO2

  • Aolong Zhang ,
  • Han Yang ,
  • Peidong Cheng ,
  • Yang Yao ,
  • Song Sun
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  • Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou University, Changzhou, Jiangsu 213164
*E-mail:

Received date: 2024-06-27

  Revised date: 2024-09-05

  Online published: 2024-09-19

Supported by

National Natural Science Foundation of China(21602019); National Local Joint Engineering Laboratory to Functional Adsorption Material Technology for the Environmental Protection(SDGC2125)

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摘要

发展了一种在可见光促进条件下, 活化烯烃与丙二酸酯、CO2的碳-羧化反应, 能够在温和的反应条件下, 以较高的收率得到一系列结构多样的1,1,3-三羧酸酯化合物. 该反应具有良好的底物适应性, 1,1-二芳基烯烃、单芳基烯烃以及连有重要药物分子片段的烯烃都能很好地兼容反应. 该反应以CO2为羧基源, 为三羧酸酯类化合物的合成提供了一个绿色、简洁高效的合成方法.

关键词： 二氧化碳; 羧基化; 烯烃双官能团化; 可见光催化

本文引用格式

张澳龙 , 杨晗 , 程佩栋 , 姚阳 , 孙松 . 可见光促进烯烃与丙二酸酯、CO2的碳-羧化反应研究[J]. 有机化学, 2024 , 44(10) : 3159 -3168 . DOI: 10.6023/cjoc202406038

Abstract

A photoredox-catalyzed cascade carbon/carboxylation of activated alkenes with malonates acetals and CO2 has been achieved, leading to a range of functionalized 1,1,3-tricarboxylates in good efficiency under mild reaction conditions. This reaction provides a facile and sustainable method for the synthesis of tricarboxylates by using CO2 as the carboxylic source.

Key words： carbon dioxide; carboxylation; alkene difunctionalization; visible-light catalyzed

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