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2025 , Vol. 45 >Issue 4: 1178 - 1193

DOI: https://doi.org/10.6023/cjoc202407033

综述与进展

金和手性磷酸共催化的不对称合成研究进展

  • 朱晓宇 ,
  • 杨诗林 ,
  • 罗宜铭 ,
  • 李文泽
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  • 沈阳化工大学 辽宁省稀土化学及应用重点实验室 沈阳 110142

收稿日期: 2024-07-18

  修回日期: 2024-09-05

  网络出版日期: 2024-10-18

基金资助

辽宁省教育厅基金(LJKMZ20220795)

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Advances of Asymmetric Synthesis Combining of Gold and Chiral Phosphoric Acid Catalysts

  • Xiaoyu Zhu ,
  • Shilin Yang ,
  • Yiming Luo ,
  • Wenze Li
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  • Liaoning Key Laboratory of Rare Earth Chemistry and Application, Shenyang University of Chemical Technology, Shenyang 110142
* E-mail:

Received date: 2024-07-18

  Revised date: 2024-09-05

  Online published: 2024-10-18

Supported by

Liaoning Provincial Department of Education Fund(LJKMZ20220795)

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摘要

均相金催化在近年来发展迅速并取得了极大进展, 然而金(I)配合物的线性结构以及Au(III)有机配合物的不稳定性限制了其在很多不对称催化反应中的应用. 将金催化与有机催化结合起来, 能够实现优势互补, 大大拓展了不对称金催化的应用范围. 手性磷酸是一种结构独特的双功能有机催化剂, 其与过渡金属联合催化, 发展了很多单一催化剂难以实现的新反应. 综述了金和手性磷酸共催化进行不对称合成的研究进展, 从抗衡阴离子导向催化、协同催化和接力催化等三个方面进行了总结探讨, 并对其发展前景进行了展望.

关键词： 金催化; 手性磷酸; 阴离子导向催化; 协同催化; 接力催化

本文引用格式

朱晓宇 , 杨诗林 , 罗宜铭 , 李文泽 . 金和手性磷酸共催化的不对称合成研究进展[J]. 有机化学, 2025 , 45(4) : 1178 -1193 . DOI: 10.6023/cjoc202407033

Abstract

Homogeneous gold catalysis has developed rapidly and made great progress in recent years, however, the linear structure of Au(I) complexes and the instability of Au(III) organic complexes limit their application in many asymmetric catalytic reactions. Combining gold with organic small molecules as cocatalysts may promote complementary advantages and greatly expand the application scope of asymmetric gold catalysis. Chiral phosphoric acid is a kind of bifunctional organic catalyst with novel structure. Combining chiral phosphoric acids with transition metals can catalyze many new reactions that are difficult to realize with a single catalyst. The asymmetric reactions catalyzed by gold and chiral phosphoric acid are summarized from three aspects, including counter anion directed catalysis, cooperative catalysis and relay catalysis, as well as the latest research progress and development prospects are also discussed.

Key words： gold catalysis; chiral phosphoric acid; anion directed catalysis; cooperative catalysis; relay catalysis

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