Advances in Design of Covalent Organic Frameworks and Their Application in Catalytic C-H Activation

doi:10. 6023/cjoc202410015

Abstract

Covalent organic frameworks (COFs) are emerging as significant porous materials in the field of catalysis, owing to their unique designability, high porosity, favorable crystallinity, and customizable pore environments. Recent advancements in COFs research have led to increased structural diversity and the exploration of various construction strategies, showcasing their remarkable application prospects in catalysis. This paper offers a comprehensive overview of common strategies employed in constructing COFs based on their fundamental structures. Additionally, we highlighted several practical applications of COFs in C-H activation, elucidating the catalytic mechanisms involved in these reactions. Finally, we explored the current challenges and issues confronting COFs in the realm of catalysis, intending to provide valuable guidance for their future development in C-H activation.

Key words: Covalent Organic Frameworks (COFs), Modification Schemes, C-H Activation

Cite this article

Wang Xuan, Liu Maochen, Zhong Yao, Song Renjie. Advances in Design of Covalent Organic Frameworks and Their Application in Catalytic C-H Activation[J]. Chinese Journal of Organic Chemistry, doi: 10. 6023/cjoc202410015.

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共价有机框架的设计及其在催化C-H活化领域的应用进展