Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (02): 254-265 .DOI: 10.6023/cjoc1103243 Previous Articles     Next Articles



计立a, 刘金强b, 钱超a, 陈新志a   

  1. a 浙江大学化学工程与生物工程学系 杭州 310027;
    b 洛阳师范学院化学化工学院 洛阳 471022
  • 收稿日期:2011-03-24 修回日期:2011-05-03 发布日期:2012-03-09
  • 通讯作者: 钱超
  • 基金资助:

    浙江省重点科技创新团队(No. 2009R50002)和中央高校基本科研业务费专项资金(No. 2011QNA4018)资助项目.

Advances in the Application of Urea-Hydrogen Peroxide to Oxidation Reactions

Ji Lia, Liu Jinqiangb, Qian Chaoa, Chen Xinzhia   

  1. a Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027;
    b College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022
  • Received:2011-03-24 Revised:2011-05-03 Published:2012-03-09
  • Supported by:

    Project supported by the Aid Program for Key Science and Technology Innovative Research Team in Zhejiang Province (No. 2009R50002) and the Fundamental Research Funds for the Central Universities of China (No. 2011QNA4018).

Oxidation reactions play important roles in organic synthesis, where hydrogen peroxide and peroxy acids are always employed as oxidants. Urea-hydrogen peroxide (UHP) is recently utilized in numerous oxidation reactions as environment- friendly solidified hydrogen peroxide, due to its advantages such as stable at room temperature, high hydrogen peroxide content (36.2%) and the potential for releasing it in a controlled manner. Several applications of UHP to organic synthesis are summarized according to reaction type, especially for epoxidation, Baeyer-Villiger oxidation, N-oxidation, oxidation of sulfides to sulfoxides and sulfones, oxidative-halogenation and so on.

Key words: urea-hydrogen peroxide (UHP), epoxidation, Baeyer-Villiger oxidation, N-oxidation, sulfones, sulfoxides, oxidative-halogenation