Synthesis, Structures of Macrocyclic Compounds and Study on Recognition for La(Ⅲ) Ion

doi:10.6023/cjoc201301062

Chin. J. Org. Chem. ›› 2013, Vol. 33 ›› Issue (08): 1798-1803.DOI: 10.6023/cjoc201301062 Previous Articles Next Articles

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大环化合物的合成、结构及其对镧(Ⅲ)离子的识别研究

欧敏^a, 邓雅欣^a, 王芳芳^a, 朱纯^a, 张奇龙^b, 朱必学^a

a 贵州大学大环及超分子化学重点实验室贵阳 550025;
b 贵阳医学院化学教研室贵阳 550004

收稿日期:2013-01-24 修回日期:2013-03-15 发布日期:2013-04-03
通讯作者: 朱必学 E-mail:sci.bxzhu@gzu.edu.cn
基金资助:
国家自然科学基金(No. 21061003);贵州省自然科学基金(No.[2012]2151)资助项目.

Synthesis, Structures of Macrocyclic Compounds and Study on Recognition for La(Ⅲ) Ion

Ou Min^a, Deng Yaxin^a, Wang Fangfang^a, Zhu Chun^a, Zhang Qilong^b, Zhu Bixue^a

a Key Laboratory of Macrocyclic and Supramolecular Chemistry, Guizhou University, Guiyang 550025;
b Department of Chemistry, Guiyang Medical College, Guiyang 550004

Received:2013-01-24 Revised:2013-03-15 Published:2013-04-03
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21061003) and the Natural Science Foundation of Guizhou Province (No.[2012]2151).

1. Synthesis, Structures of Macrocyclic Compounds and Study on Recognition for La(Ⅲ) Ion.PDF(234KB)

Abstract

[1+1] Schiff base macrocyclic compound 3 has been synthesized from precursor 1 [1,2-bis(2'-formacyl- phenoxy)ethane] and precursor 2[2-resorcinol-bis(4-aminophenyl)ether] via condensation and cyclization using Ba²⁺ as template. The macrocycle 3 was further reduced giving macrocyclic compound 4, and the structures were characterized by ¹H NMR, IR, MS and elemental analysis, respectively. The X-ray single crystal analysis reveals that the macrocycle 3 has a folding structure, and 4 shows a twisted unfolding structure. The study for the reaction of the macrocyclic compound 3 or 4 with a series of the rare earth ions is performed by UV-Vis absorption spectra technique, and the results show that the macrocycle 3 displayed a selective recognition for La³⁺ ion. Moreover, the JOB plot exhibited a 1:1 (host:guest) stoichiometry between the host 3 and La³⁺, and the binding constant (K) was determined using UV-vis titration method, K=7.59×10³.

Key words: macrocyclic compound, crystal structure, La(Ⅲ) ion, recognition

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Ou Min, Deng Yaxin, Wang Fangfang, Zhu Chun, Zhang Qilong, Zhu Bixue. Synthesis, Structures of Macrocyclic Compounds and Study on Recognition for La(Ⅲ) Ion[J]. Chin. J. Org. Chem., 2013, 33(08): 1798-1803.

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大环化合物的合成、结构及其对镧(Ⅲ)离子的识别研究

Synthesis, Structures of Macrocyclic Compounds and Study on Recognition for La(Ⅲ) Ion

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