Boron-Based Lewis Acid Transition Metal Complexes as Potential Bifunctional Catalysts

doi:10.6023/cjoc201703002

Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (9): 2187-2202.DOI: 10.6023/cjoc201703002 Previous Articles Next Articles

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硼基路易斯酸-过渡金属配合物:新型双功能催化剂（英文）

李胤午^a, 张鉴予^a, 舒思桅^b, 邵佑湘^a, 刘艳^b, 柯卓锋^a

a 中山大学材料科学与工程学院聚合物复合材料及功能材料教育部重点实验室广州 510275;
b 广东工业大学化学工程与轻工业学院广州 510006

收稿日期:2017-03-01 修回日期:2017-05-27 发布日期:2017-07-14
通讯作者: 刘艳, 柯卓锋 E-mail:yanliu@gdut.edu.cn;kezhf3@mail.sysu.edu.cn
基金资助:
国家自然科学基金（Nos.21673301，21473261，21502023）、广东省自然科学杰出青年基金（No.2015A030306027）资助项目.

Boron-Based Lewis Acid Transition Metal Complexes as Potential Bifunctional Catalysts

Li Yinwu^a, Zhang Jianyu^a, Shu Siwei^b, Shao Youxiang^a, Liu Yan^b, Ke Zhuofeng^a

a Key Laboratory for Polymeric Composite & Functional Materials of Ministry of Education, School of Materials Science & Engineering, Sun Yat-sen University, Guangzhou 510275;
b School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006

Received:2017-03-01 Revised:2017-05-27 Published:2017-07-14
Contact: 10.6023/cjoc201703002 E-mail:yanliu@gdut.edu.cn;kezhf3@mail.sysu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21673301, 21473261, 21502023) and the Guangdong Natural Science Funds for Distinguished Young Scholar (No. 2015A030306027).

Lewis acid-transition metal (LA-TM) complexes, with the LA site functions as an electron acceptor and the TM center functions as an electron donor, have been emerging as a new type of bifunctional catalysts lately, different from traditional transition metal bifunctional catalysts. Due to their rapid developments recently, the boron-based LA-TM complexes, which are divided into three major types, the sp³, sp², and sp boron-based complexes, are reviewed in this paper according to their binding features. Reactions promoted by this new type of LA-TM bifunctional catalysts have been surveyed, including migration reactions, activation of H-H/E-H/E-E bonds, hydrogenations, hydrosilylations, and transfer dehydrogenation reactions etc. This overview of boron-based LA-TM complexes could provide valuable information to explore the new horizon in LA-TM bifunctional catalysis.

Key words: Lewis acid, transition metal, bifunctional catalysis, boron, activation, hydrogenation, dehydrogenation

Cite this article

Li Yinwu, Zhang Jianyu, Shu Siwei, Shao Youxiang, Liu Yan, Ke Zhuofeng. Boron-Based Lewis Acid Transition Metal Complexes as Potential Bifunctional Catalysts[J]. Chin. J. Org. Chem., 2017, 37(9): 2187-2202.

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硼基路易斯酸-过渡金属配合物:新型双功能催化剂（英文）

Boron-Based Lewis Acid Transition Metal Complexes as Potential Bifunctional Catalysts

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